Cu/aminoclay/reduced graphene oxide nanohybrid: an efficient catalyst for N-arylation of nucleobases and other N-heterocycles under ultrasonic irradiation

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Behrouz Somayeh; Soltani Rad Mohammad Navid

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Journal: Journal of Applied Research in Chemistry Year:2019 | Volume:13 | Issue:1 Page(s): 135-148

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Title

Cu/aminoclay/reduced graphene oxide nanohybrid: an efficient catalyst for N-arylation of nucleobases and other N-heterocycles under ultrasonic irradiation

Author(s)

Behrouz Somayeh | Soltani Rad Mohammad Navid | Issue Writer Certificate

Keywords

N-ArylationQ1

Aryl halidQ1

Nano-catalystQ1

NucleobaseQ1

Ultrasonic irradiationQ2

Abstract

An ultrasonic promoted facile and convenient procedure for the synthesis of N-aryl Nucleobases and other N-heterocyclic derivatives using Cu/aminoclay/reduced graphene oxide nanohybrid as an efficient heterogeneous Nano-catalyst has been described. In this approach, room temperature ultrasonic mediated N-Arylation reaction of Nucleobases and other N-heterocyclic compounds with Aryl halides (bromide and iodide) bearing diverse functionalities catalyzed by Cu/aminoclay/reduced graphene oxide nanohybrid in the presence of Cs2CO3 in DMSO at room temperature furnishes the corresponding N-aryl derivatives in good to excellent yields. Utilizing Ultrasonic irradiation technique provided the dramatic improvements in terms of higher yields and shorter reaction times compared with conventional heating method. The use of mild reaction conditions, short reaction time, recoverability and reusability of catalyst, and simple purification process are important advantages of the present method.

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APA: Copy

Behrouz, Somayeh, & Soltani Rad, Mohammad Navid. (2019). Cu/aminoclay/reduced graphene oxide nanohybrid: an efficient catalyst for N-arylation of nucleobases and other N-heterocycles under ultrasonic irradiation. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 13(1 ), 135-148. SID. https://sid.ir/paper/180135/en

Vancouver: Copy

Behrouz Somayeh, Soltani Rad Mohammad Navid. Cu/aminoclay/reduced graphene oxide nanohybrid: an efficient catalyst for N-arylation of nucleobases and other N-heterocycles under ultrasonic irradiation. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2019;13(1 ):135-148. Available from: https://sid.ir/paper/180135/en

IEEE: Copy

Somayeh Behrouz, and Mohammad Navid Soltani Rad, “Cu/aminoclay/reduced graphene oxide nanohybrid: an efficient catalyst for N-arylation of nucleobases and other N-heterocycles under ultrasonic irradiation,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 13, no. 1 , pp. 135–148, 2019, [Online]. Available: https://sid.ir/paper/180135/en

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