THERMODEGRADATION KINETICS OF POLY(METHYL METHACRYLATE)/SILVERNANOCOMPOSITES SYNTHESIZED VIA IN-SITU PHOTOINIFERTER-MEDIATEDPHOTOPOLYMERIZATION

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Makvandi Pooyan; Nikfarjam Nasser; JAMALEDIN REZVAN; TAHERI QAZVINI NADER

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Journal: Journal of Applied Research in Chemistry Year:2018 | Volume:12 | Issue:2 Page(s): 159-168

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Title

THERMODEGRADATION KINETICS OF POLY(METHYL METHACRYLATE)/SILVERNANOCOMPOSITES SYNTHESIZED VIA IN-SITU PHOTOINIFERTER-MEDIATEDPHOTOPOLYMERIZATION

Author(s)

Makvandi Pooyan | Nikfarjam Nasser | JAMALEDIN REZVAN | TAHERI QAZVINI NADER | Issue Writer Certificate

Keywords

PMMA/SILVER NANOCOMPOSITESQ1

POLYMER NETWORKSQ1

PHOTOINIFERTERQ1

PHOTOPOLYMERIZATIONQ1

ACTIVATION ENERGYQ1

THERMAL STABILITYQ1

DEGRADATION KINETICSQ1

Abstract

Here, we report thermodegradation of poly(methyl methacrylate)/silver nanoparticle(PMMA/AgNP) nanocomposite networks synthesized by in-situ PHOTOINIFERTER-mediatedphotopolymerization. The nanocomposite networks were prepared in the presence of 0. 5 wt. %of AgNP and various amounts of allyl methacrylate (0, 1, 5, 10 wt. %) as crosslinking agent. Thekinetic studies of thermodegradation of the nanocomposite networks by two isoconversionalmethods, Flynn-Wall-Ozawa and Kissinger– Akahira– Sunose, showed that AgNP had a dual effecton thermal degradation of PMMA networks; at early stages, AgNP promoted the degradationof the nanocomposites while in the subsequent stages maintained the polymer stability againstthermal degradation.

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APA: Copy

Makvandi, Pooyan, Nikfarjam, Nasser, JAMALEDIN, REZVAN, & TAHERI QAZVINI, NADER. (2018). THERMODEGRADATION KINETICS OF POLY(METHYL METHACRYLATE)/SILVERNANOCOMPOSITES SYNTHESIZED VIA IN-SITU PHOTOINIFERTER-MEDIATEDPHOTOPOLYMERIZATION. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 12(2 ), 159-168. SID. https://sid.ir/paper/180174/en

Vancouver: Copy

Makvandi Pooyan, Nikfarjam Nasser, JAMALEDIN REZVAN, TAHERI QAZVINI NADER. THERMODEGRADATION KINETICS OF POLY(METHYL METHACRYLATE)/SILVERNANOCOMPOSITES SYNTHESIZED VIA IN-SITU PHOTOINIFERTER-MEDIATEDPHOTOPOLYMERIZATION. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2018;12(2 ):159-168. Available from: https://sid.ir/paper/180174/en

IEEE: Copy

Pooyan Makvandi, Nasser Nikfarjam, REZVAN JAMALEDIN, and NADER TAHERI QAZVINI, “THERMODEGRADATION KINETICS OF POLY(METHYL METHACRYLATE)/SILVERNANOCOMPOSITES SYNTHESIZED VIA IN-SITU PHOTOINIFERTER-MEDIATEDPHOTOPOLYMERIZATION,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 12, no. 2 , pp. 159–168, 2018, [Online]. Available: https://sid.ir/paper/180174/en

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