INVESTIGATION ON THE INFLUENCE OF SILANE COUPLING AGENT STRUCTURE ON THE PROPERTIES OF NANO-SILICA FILLED RUBBER COMPOUND

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MALEKZADEH MERCEDEH; NOURI HESAM; FARAHANI MONA

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Journal: Journal of Applied Research in Chemistry Year:2010 | Volume:3 | Issue:12 Page(s): 41-45

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Title

INVESTIGATION ON THE INFLUENCE OF SILANE COUPLING AGENT STRUCTURE ON THE PROPERTIES OF NANO-SILICA FILLED RUBBER COMPOUND

Author(s)

MALEKZADEH MERCEDEH | NOURI HESAM | FARAHANI MONA | Issue Writer Certificate

Keywords

SILANE COUPLING AGENTQ3

NANO-SILICAQ3

NR/SBRQ3

VAN DER WAALS INTERACTIONQ3

P-P INTERACTIONQ3

Abstract

SILANE COUPLING AGENT has long been used to enhance degree of reinforcement of silica in rubber matrix. Recently various types of these coupling agents have been developed and commercialized. In the present study, two new SILANE COUPLING AGENTs were introduced as decyloxytriethylsilane and 5, 11, 17-Tritertbutyl- 23-trimethylsilylethynyl-25, 26, 27, 28-tetrapropoxy calix (4) aren to compare the effect of generating VAN DER WAALS INTERACTION between filler and polymer matrix that was originated by decyloxytriethylsilane in comparison with P-P INTERACTIONs that was due to 5, 11, 17-Tritertbutyl-23-trimethylsilylethynyl-25, 26, 27, 28- tetrapropoxy calix (4) aren. Cure characteristics and physicomechanical properties of a NANO-SILICA filled NR/ SBR polymer based compounds using these two agents were investigated and compared with commercialized Si69. Distribution of the filler in the rubber matrix was considered by scanning electron microscopy. These two suggestions were presented coupling agent effects. Decyloxytriethylsilane was shown better results due to the reduction of curative absorption and VAN DER WAALS INTERACTIONs between filler and polymer matrix in comparison with P-P INTERACTIONs that was originated by the other coupling agent.

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APA: Copy

MALEKZADEH, MERCEDEH, NOURI, HESAM, & FARAHANI, MONA. (2010). INVESTIGATION ON THE INFLUENCE OF SILANE COUPLING AGENT STRUCTURE ON THE PROPERTIES OF NANO-SILICA FILLED RUBBER COMPOUND. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 3(12), 41-45. SID. https://sid.ir/paper/180180/en

Vancouver: Copy

MALEKZADEH MERCEDEH, NOURI HESAM, FARAHANI MONA. INVESTIGATION ON THE INFLUENCE OF SILANE COUPLING AGENT STRUCTURE ON THE PROPERTIES OF NANO-SILICA FILLED RUBBER COMPOUND. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2010;3(12):41-45. Available from: https://sid.ir/paper/180180/en

IEEE: Copy

MERCEDEH MALEKZADEH, HESAM NOURI, and MONA FARAHANI, “INVESTIGATION ON THE INFLUENCE OF SILANE COUPLING AGENT STRUCTURE ON THE PROPERTIES OF NANO-SILICA FILLED RUBBER COMPOUND,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 3, no. 12, pp. 41–45, 2010, [Online]. Available: https://sid.ir/paper/180180/en

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