Applying the Mechanochemical Reaction of Cation Exchange for Green Synthesis of an Organometallic Coordination Polymer Nanofibers

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MORADI ZH.; AKHBARI K.

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Journal: NANOSCALE Year:2020 | Volume:6 | Issue:4 Page(s): 1-10

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Information Journal Paper

Title

Applying the Mechanochemical Reaction of Cation Exchange for Green Synthesis of an Organometallic Coordination Polymer Nanofibers

Author(s)

MORADI ZH. | AKHBARI K. | Issue Writer Certificate

Keywords

Coordination PolymerQ1

OrganometallicQ1

SonochemicalQ1

MechanochemicalQ1

NanostructureQ1

Abstract

Nanostructures of [Zn(BPD)(H2O)]n (1), (H2BPD = 1, 1'-biphenyl-2, 2'-dicarboxylic acid) supramolecular polymer were synthesized by the Sonochemical process. The solid-state conversion of compound 1 Nanostructures to nanofibers of [Ag2(BPD)]n (2) Coordination Polymer was investigated by cation exchange reaction of compound 1 with AgNO3. X-ray diffraction (XRD) analyzes and thermogravimetric and differential thermal analyses (TG-DTA) have shown that this conversion is irreversible. Consideration the crystal structure of these two compounds, which were reported previously, shows that during this process, the ZnO4 coordination sphere in 1 changed to AgO3Ag2˙ ˙ ˙ C6 in 2, thus an Organometallic compound was synthesized during this solid-state Mechanochemical reaction.

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APA: Copy

MORADI, ZH., & AKHBARI, K.. (2020). Applying the Mechanochemical Reaction of Cation Exchange for Green Synthesis of an Organometallic Coordination Polymer Nanofibers. NANOSCALE, 6(4 ), 1-10. SID. https://sid.ir/paper/257038/en

Vancouver: Copy

MORADI ZH., AKHBARI K.. Applying the Mechanochemical Reaction of Cation Exchange for Green Synthesis of an Organometallic Coordination Polymer Nanofibers. NANOSCALE[Internet]. 2020;6(4 ):1-10. Available from: https://sid.ir/paper/257038/en

IEEE: Copy

ZH. MORADI, and K. AKHBARI, “Applying the Mechanochemical Reaction of Cation Exchange for Green Synthesis of an Organometallic Coordination Polymer Nanofibers,” NANOSCALE, vol. 6, no. 4 , pp. 1–10, 2020, [Online]. Available: https://sid.ir/paper/257038/en

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