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Information Journal Paper

Title

TINE FILM SYNTHESIS OF LIMN2O4 ON THE GRAPHITE AND CRYSTALLINE, MORPHOLOGY AND ELECTROCHEMICAL PROPERTIES

Pages

  67-76

Abstract

 Stocumetry, crystallity and MORPHOLOGY’s influence on electrochemical properties on active material reacted to syntheses method completely. Spinal LITHIUM MANGANESE OXIDE having the formula LiXMn2O4 (X=0.3, 0.4 and 0.5) was synthesized in the form of thin film on a GRAPHITE substrate by electrochemical method using manganese sulfate and LITHIUM hydroxide as starting material. The LITHIUM and manganese concentrations in the resulting materials were analyzed using an inductively coupled plasma spectrometer (ICP). X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to analyze the structures of the electrodes. Electrochemical behavior of active material syntheses was examined by charager/discharge test with LiMn2O4 as CATHODE electrode, LITHIUM as anode electrode and A solution of 1 M LITHIUM perchlorate (LiClO4) in a mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) at a ratio of 1:1 as the electrolyte by constant current of 0.1 mA/cm2, for the range of 2.5 to 4.3 V at room temperature. Furthermore, electrochemical characterization of the prepared active material were analyzed using cyclic voltammetry (CV) in the voltage range 3.5-4.6 V with rate 0.15 mV/s in electrolyte mentioned above. Result show optimum time for heating option is 20 minute and material with stocumetry ratio X=0.5 having better behavior than other ratios.

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  • Cite

    APA: Copy

    JAMSHIDIRAD, R.A., GHAEMI, M., & HAGHIGHAT PAZHOUH, H.R.. (2008). TINE FILM SYNTHESIS OF LIMN2O4 ON THE GRAPHITE AND CRYSTALLINE, MORPHOLOGY AND ELECTROCHEMICAL PROPERTIES . NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 27(2), 67-76. SID. https://sid.ir/paper/26186/en

    Vancouver: Copy

    JAMSHIDIRAD R.A., GHAEMI M., HAGHIGHAT PAZHOUH H.R.. TINE FILM SYNTHESIS OF LIMN2O4 ON THE GRAPHITE AND CRYSTALLINE, MORPHOLOGY AND ELECTROCHEMICAL PROPERTIES . NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2008;27(2):67-76. Available from: https://sid.ir/paper/26186/en

    IEEE: Copy

    R.A. JAMSHIDIRAD, M. GHAEMI, and H.R. HAGHIGHAT PAZHOUH, “TINE FILM SYNTHESIS OF LIMN2O4 ON THE GRAPHITE AND CRYSTALLINE, MORPHOLOGY AND ELECTROCHEMICAL PROPERTIES ,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 27, no. 2, pp. 67–76, 2008, [Online]. Available: https://sid.ir/paper/26186/en

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