KINETICS OF HDS REACTION FOR SOUTH PARS GAS CONDENSATES

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MOHAMMADI M.; TAJERIAN M.; SHOKRI S.; DEHGHANI A.; MAHDIPOUR H.R.

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Journal: Nashrieh Shimi va Mohandesi Shimi Iran Year:2008 | Volume:27 | Issue:1 Page(s): 93-101

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Title

KINETICS OF HDS REACTION FOR SOUTH PARS GAS CONDENSATES

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Keywords

HYDRODESULFURIZATIONQ3

GAS CONDENSATEQ2

REACTIONQ2

KINETICSQ2

CATALYSTQ3

THIOPHENEQ3

Abstract

In this research, a systematic investigation was carried out to determine KINETICS of HDS REACTION of Iranian GAS CONDENSATE using a commercial CATALYST (Co-Mo/ g -Al2O3). In this way, process conditions were optimized. Experiments were carried out in a trickle bed micro reactor (10 cc CATALYST) at 280-3400C, 40-50 bar, Liquid hourly space velocity (LHSV) of 1-5 h –1, H2/Oil ratio of 125 nl/l. Prior to the KINETICS tests, by some basic tests, mass transfer effects on chemical REACTIONs were evaluated, and it is found that pore diffusion and film diffusion resistances have a slight effect on the KINETICS of chemical REACTION, within the operating conditions. Hence, KINETICS of HDS REACTION was determined by using THIOPHENE as a reference sulfur component, in the form of power low model. The results indicated that THIOPHENE HDS REACTION order in GAS CONDENSATE feed was 1.3. Also, HDS REACTION activation energy was determined to be 77.55 kj/mol. The results of this KINETICS model and its simulation can use in optimization of HDS units process conditions and prediction of product specifications with new feeds and different process conditions. It is also useful for designing the reactor of new HDS plants.

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APA: Copy

MOHAMMADI, M., TAJERIAN, M., SHOKRI, S., DEHGHANI, A., & MAHDIPOUR, H.R.. (2008). KINETICS OF HDS REACTION FOR SOUTH PARS GAS CONDENSATES. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 27(1), 93-101. SID. https://sid.ir/paper/26377/en

Vancouver: Copy

MOHAMMADI M., TAJERIAN M., SHOKRI S., DEHGHANI A., MAHDIPOUR H.R.. KINETICS OF HDS REACTION FOR SOUTH PARS GAS CONDENSATES. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2008;27(1):93-101. Available from: https://sid.ir/paper/26377/en

IEEE: Copy

M. MOHAMMADI, M. TAJERIAN, S. SHOKRI, A. DEHGHANI, and H.R. MAHDIPOUR, “KINETICS OF HDS REACTION FOR SOUTH PARS GAS CONDENSATES,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 27, no. 1, pp. 93–101, 2008, [Online]. Available: https://sid.ir/paper/26377/en

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