Synthesis of benzoxanthene-3, 4-carboxilic anhydride and application in dye-sensitized solar cell

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Senobari Navid; Gharanjig Kamaledin; Najafi Farhud; MORADIAN SIAMAK

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Journal: ADVANCED MATERIALS AND NOVEL COATINGS Year:2019 | Volume:7 | Issue:27 Page(s): 1887-1897

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Title

Synthesis of benzoxanthene-3, 4-carboxilic anhydride and application in dye-sensitized solar cell

Author(s)

Senobari Navid | Gharanjig Kamaledin | Najafi Farhud | MORADIAN SIAMAK | Issue Writer Certificate

Keywords

Synthesis

Benzoxanthene-3

4-carboxilic anhydride

Dye-sensitized solar cells

Photovoltaic Parameters

Abstract

In the present study, an organic dye based on Benzoxanthene-3, 4-carboxilic anhydride was synthesized to be used in dye-sensitized solar cell. In order to do that, acenaphthene was utilized as the main reagent and a series of consecutive reactions were conducted to yield the mentioned benxoxanthene-3, 4-carboxilic anhydride, including bromination, nitration, oxidation, reduction, phenolation and cyclization. In order to purify the intermediates and the final dye, recrystallization was done and followed by column chromatography and the materials were analyzed by Fourier Transform Infrared Spectroscopy, Nuclear Magnetic Resonance Spectroscopy, UV-Vis Spectrophotometery and Mass Spectroscopy. Finally, the synthesized dye was used as a sensitizer in a dye-sensitized solar cell. Photovoltaic Parameters of the fabricated dye-sensitized solar cell were investigated by solar simulator and were compared to the cell fabricated by the dye N719 as a reference. Results show that the ratio of the power conversion efficiency of the cell based on the Benzoxanthene-3, 4-carboxilic anhydride to the corresponding value of the cell based on N719 was approximately 34%.

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APA: Copy

Senobari, Navid, Gharanjig, Kamaledin, Najafi, Farhud, & MORADIAN, SIAMAK. (2019). Synthesis of benzoxanthene-3, 4-carboxilic anhydride and application in dye-sensitized solar cell. ADVANCED MATERIALS AND NOVEL COATINGS, 7(27 ), 1887-1897. SID. https://sid.ir/paper/270246/en

Vancouver: Copy

Senobari Navid, Gharanjig Kamaledin, Najafi Farhud, MORADIAN SIAMAK. Synthesis of benzoxanthene-3, 4-carboxilic anhydride and application in dye-sensitized solar cell. ADVANCED MATERIALS AND NOVEL COATINGS[Internet]. 2019;7(27 ):1887-1897. Available from: https://sid.ir/paper/270246/en

IEEE: Copy

Navid Senobari, Kamaledin Gharanjig, Farhud Najafi, and SIAMAK MORADIAN, “Synthesis of benzoxanthene-3, 4-carboxilic anhydride and application in dye-sensitized solar cell,” ADVANCED MATERIALS AND NOVEL COATINGS, vol. 7, no. 27 , pp. 1887–1897, 2019, [Online]. Available: https://sid.ir/paper/270246/en

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