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Information Journal Paper

Title

THE INVESTIGATION OF EQUILIBRIA IN SOLUTION

Pages

  522-534

Abstract

 This contribution describes the practical and computational aspects relevant for the quantitative analysis of chemical equilibria. First a systematic nomenclature based on stability constants is introduced. Next, practical aspects of potentiometric pH TITRATIONs and spectrophotometric TITRATIONs are discussed. The description of the computational aspects includes the Newton- Raphson algorithm that allows the computation of all species concentrations for a given model, set of formation constants and total component concentrations. The second computational part introduces the Newton-Gauss algorithm for non-linear data fitting. Three practical examples illustrate all the above. They include the spectrophotometric investigations of the interaction of Bi(III) with Cl-, of Cu(II) with EDTA and the potentiometric investigation of the Zn(II) ethylenediamine system. All Matlab softwares for the data generation and analysis are available from the authors.

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  • Cite

    APA: Copy

    MAEDER, M., & ABD ELAHI, H.. (2008). THE INVESTIGATION OF EQUILIBRIA IN SOLUTION. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 5(4), 522-534. SID. https://sid.ir/paper/282256/en

    Vancouver: Copy

    MAEDER M., ABD ELAHI H.. THE INVESTIGATION OF EQUILIBRIA IN SOLUTION. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2008;5(4):522-534. Available from: https://sid.ir/paper/282256/en

    IEEE: Copy

    M. MAEDER, and H. ABD ELAHI, “THE INVESTIGATION OF EQUILIBRIA IN SOLUTION,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 5, no. 4, pp. 522–534, 2008, [Online]. Available: https://sid.ir/paper/282256/en

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