FORMATION OF A SIX-COORDINATE FAC-[RE(CO)3]+
 COMPLEX BY THE N-C BOND CLEAVAGE OF A POTENTIALLY TETRADENTATE LIGAND

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BOOYSEN I.; GERBER T.I.A.; HOSTEN E.; MAYER P.

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ISSN: 2588-4824

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2008 | Volume:5 | Issue:4 Page(s): 689-693

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Title

FORMATION OF A SIX-COORDINATE FAC-[RE(CO)3]+ COMPLEX BY THE N-C BOND CLEAVAGE OF A POTENTIALLY TETRADENTATE LIGAND

Author(s)

BOOYSEN I. | GERBER T.I.A. | HOSTEN E. | MAYER P. | Issue Writer Certificate

Keywords

RHENIUM (I)

CLEAVAGE OF N-C BOND

DIAMINOAMIDE

CRYSTAL STRUCTURE

Abstract

The rhenium (I) compound fac- [Re (CO)3(daa)]. Hpab.H2O (Hpab = N,N’- (1,2-phenylene) bis (2’-aminobenzamide); Hdaa=2- amino-N- (2-aminophenyl) benzamide) was synthesized from the reaction of [Re(CO)5Br] with two equivalent of Hpab in toluene. The monoanionic tridentate ligand daa was formed by the rhenium-mediated cleavage of an amido N-C bond of the potentially tetradentate ligand Hpab. The compound was characterized by IR spectroscopy and X-ray crystallography, and daa is coordinated as a DIAMINOAMIDE via three nitrogen-donor atoms.

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APA: Copy

BOOYSEN, I., GERBER, T.I.A., HOSTEN, E., & MAYER, P.. (2008). FORMATION OF A SIX-COORDINATE FAC-[RE(CO)₃]⁺ COMPLEX BY THE N-C BOND CLEAVAGE OF A POTENTIALLY TETRADENTATE LIGAND. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 5(4), 689-693. SID. https://sid.ir/paper/282264/en

Vancouver: Copy

BOOYSEN I., GERBER T.I.A., HOSTEN E., MAYER P.. FORMATION OF A SIX-COORDINATE FAC-[RE(CO)₃]⁺ COMPLEX BY THE N-C BOND CLEAVAGE OF A POTENTIALLY TETRADENTATE LIGAND. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2008;5(4):689-693. Available from: https://sid.ir/paper/282264/en

IEEE: Copy

I. BOOYSEN, T.I.A. GERBER, E. HOSTEN, and P. MAYER, “FORMATION OF A SIX-COORDINATE FAC-[RE(CO)₃]⁺ COMPLEX BY THE N-C BOND CLEAVAGE OF A POTENTIALLY TETRADENTATE LIGAND,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 5, no. 4, pp. 689–693, 2008, [Online]. Available: https://sid.ir/paper/282264/en

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