مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Information Journal Paper

Title

HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND PHOTOLUMINESCENCE OF [HGCL2(C6NO2H5)]NN[HGCL2]N(C6NO2H5)

Pages

  510-515

Abstract

 The first example of ISONICOTINIC ACID compounds with infinite MERCURY halide chains, [HgCl2(C6NO2H5)]n n[HgCl2]n(C6NO2H5) (1), was synthesized through HYDROTHERMAL REACTIONs and structurally characterized by X-ray single crystal diffraction. Compound 1 features a one-dimensional (1-D) motif, based on infinite 1-D [HgCl2(C6NO2H5)]n chains, neutral HgCl2 moieties and isolated ISONICOTINIC ACID molecules. The [HgCl2(C6NO2H5)]n chains, HgCl2 moieties and ISONICOTINIC ACID molecules are interlinked by hydrogen bonds and π-π interactions to give a two-dimensional supramolecular layer. Photoluminescent investigation reveals that the title compound exhibits a strong emission in blue region. The emission band is identified as the π-π* transitions of the ISONICOTINIC ACID moieties.

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    • Cite

    APA: Copy

    CHEN, W.T., YING, S.M., LIU, D.S., LIU, J.H., & KUANG, H.M.. (2010). HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND PHOTOLUMINESCENCE OF [HGCL2(C6NO2H5)]NN[HGCL2]N(C6NO2H5). JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(2), 510-515. SID. https://sid.ir/paper/282396/en

    Vancouver: Copy

    CHEN W.T., YING S.M., LIU D.S., LIU J.H., KUANG H.M.. HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND PHOTOLUMINESCENCE OF [HGCL2(C6NO2H5)]NN[HGCL2]N(C6NO2H5). JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(2):510-515. Available from: https://sid.ir/paper/282396/en

    IEEE: Copy

    W.T. CHEN, S.M. YING, D.S. LIU, J.H. LIU, and H.M. KUANG, “HYDROTHERMAL SYNTHESIS, CRYSTAL STRUCTURE AND PHOTOLUMINESCENCE OF [HGCL2(C6NO2H5)]NN[HGCL2]N(C6NO2H5),” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 2, pp. 510–515, 2010, [Online]. Available: https://sid.ir/paper/282396/en

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