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Information Journal Paper

Title

SYNTHESIS AND CHARACTERIZATION OF HIPPURATE-LAYERED DOUBLE HYDROXIDE NANOHYBRID AND INVESTIGATION OF ITS RELEASE PROPERTY

Pages

  42-51

Abstract

 The anion of HIPPURIC ACID, hippurate (A-), as an organic guest was intercalated into the interlayers of ANIONIC CLAY, Zn/Al HYDROTALCITE-like or LAYERED DOUBLE HYDROXIDES (LDH) host by direct co-precipitation method from aqueous solution for the formation of new NANOHYBRID compounds, Zn/Al-hippurate NANOHYBRIDs (ZAHs). Various Zn/Al molar ratios (R) = 3-5 and concentrations of HA (0.06-0.15 M) were used for the synthesis. ZAHs synthesized, using 0.15 M HA, was found to give well-ordered layered NANOHYBRID materials with an increase of the basal spacing to 19.6-21.0 Å compared to 8.8-9.0 Å in the LDHs. The increase in the basal spacing is due to the insertion of A- organic moiety into the LDH interlayers. Formation of the host-guest type of material was confirmed by XRD, FTIR, TGA/DTG and compositional analysis. The release of the intercalated guest was found to be tunable in a controlled manner by Zn/Al molar ratio and is governed by pseudo-second order kinetics. Thus, by varying the experimental conditions, the release property of the guest anion can be tailored as required.

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    APA: Copy

    HUSSEIN, M.Z., BAHAR, F.A., & YAHYA, H.J.. (2010). SYNTHESIS AND CHARACTERIZATION OF HIPPURATE-LAYERED DOUBLE HYDROXIDE NANOHYBRID AND INVESTIGATION OF ITS RELEASE PROPERTY. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(SUPPLEMENT), 42-51. SID. https://sid.ir/paper/282399/en

    Vancouver: Copy

    HUSSEIN M.Z., BAHAR F.A., YAHYA H.J.. SYNTHESIS AND CHARACTERIZATION OF HIPPURATE-LAYERED DOUBLE HYDROXIDE NANOHYBRID AND INVESTIGATION OF ITS RELEASE PROPERTY. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(SUPPLEMENT):42-51. Available from: https://sid.ir/paper/282399/en

    IEEE: Copy

    M.Z. HUSSEIN, F.A. BAHAR, and H.J. YAHYA, “SYNTHESIS AND CHARACTERIZATION OF HIPPURATE-LAYERED DOUBLE HYDROXIDE NANOHYBRID AND INVESTIGATION OF ITS RELEASE PROPERTY,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. SUPPLEMENT, pp. 42–51, 2010, [Online]. Available: https://sid.ir/paper/282399/en

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