SYNTHETIC, STRUCTURAL AND BIOLOGICAL STUDIES OF ORGANOTIN(IV) COMPLEXES OF SCHIFF BASES DERIVED FROM PYRROL-2-CARBOXALDEHYDE

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SINGH K.; DHARAMPAL -; DHIMAN S.S.

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:1 Page(s): 243-250

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Information Journal Paper

Title

SYNTHETIC, STRUCTURAL AND BIOLOGICAL STUDIES OF ORGANOTIN(IV) COMPLEXES OF SCHIFF BASES DERIVED FROM PYRROL-2-CARBOXALDEHYDE

Author(s)

SINGH K. | DHARAMPAL - | DHIMAN S.S. | Issue Writer Certificate

Keywords

ORGANOTIN(IV) COMPLEXES

S-TRIAZOLES

SCHIFF BASES

ANTIFUNGAL AND ANTIBACTERIAL ACTIVITIES

Abstract

Some new organotin(IV) complexes having general formulae R2MCl[L] and R2M[L]2 were synthesized by the reactions of Me2MCl2 with SCHIFF BASES [5-Mercapto-4-(pyrrolcarboxalideneamino)-s-triazole, 5-Mercapto-3-methyl-4-(2-pyrrolcarboxalideneamino)- s-triazole, 3-Ethyl-5-mercapto-4-(2-pyrrolcarboxalideneamino)-s-triazole] in 1:1 and 1:2 molar ratios. All of the compounds were characterized by elemental analysis, molar conductance, IR, UV, 1H, 13C and 119Sn NMR spectral studies. The IR and 1H NMR spectral data suggest the involvement of azomethine nitrogen in coordination with the central metal atom. With the help of the above-mentioned spectral studies, penta and hexacoordinated environments around the central metal atoms in the 1:1 and 1:2 complexes, respectively, have been proposed. Finally, the free ligands and their metal complexes were tested in vitro against some pathogenic bacteria and fungi to assess their antimicrobial properties.

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APA: Copy

SINGH, K., DHARAMPAL, -, & DHIMAN, S.S.. (2010). SYNTHETIC, STRUCTURAL AND BIOLOGICAL STUDIES OF ORGANOTIN(IV) COMPLEXES OF SCHIFF BASES DERIVED FROM PYRROL-2-CARBOXALDEHYDE. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(1), 243-250. SID. https://sid.ir/paper/282419/en

Vancouver: Copy

SINGH K., DHARAMPAL -, DHIMAN S.S.. SYNTHETIC, STRUCTURAL AND BIOLOGICAL STUDIES OF ORGANOTIN(IV) COMPLEXES OF SCHIFF BASES DERIVED FROM PYRROL-2-CARBOXALDEHYDE. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(1):243-250. Available from: https://sid.ir/paper/282419/en

IEEE: Copy

K. SINGH, - DHARAMPAL, and S.S. DHIMAN, “SYNTHETIC, STRUCTURAL AND BIOLOGICAL STUDIES OF ORGANOTIN(IV) COMPLEXES OF SCHIFF BASES DERIVED FROM PYRROL-2-CARBOXALDEHYDE,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 1, pp. 243–250, 2010, [Online]. Available: https://sid.ir/paper/282419/en

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