THERMODYNAMIC STUDY OF THE INTERACTION OF CO(II)-SCHIFF BASE COMPLEXES WITH PHOSPHINES

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ASADI M.; MOHAMMADIKISH M.; MOHAMMADI K.

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ISSN: 2588-4824

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:1 Page(s): 195-201

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Title

THERMODYNAMIC STUDY OF THE INTERACTION OF CO(II)-SCHIFF BASE COMPLEXES WITH PHOSPHINES

Author(s)

ASADI M. | MOHAMMADIKISH M. | MOHAMMADI K. | Issue Writer Certificate

Keywords

COBALT

SCHIFF BASE

EQUILIBRIUM CONSTANT

THERMODYNAMIC PARAMETERS

Abstract

The EQUILIBRIUM CONSTANTs and the THERMODYNAMIC PARAMETERS for the interaction of CoLx (L1 = 5-OMe-salabza, L2 = salabza, L3 = 5-Br-salabza and L4 = 5-NO2-salabza) as acceptors, with phosphines (PBu3, PPh2Me) as donors in dichloromethane were studied. This was performed by using UV-Vis spectrophotometry titration for 1:1 adduct formation of the selected complexes at various temperatures (T = 283-298 K). The trend of the adduct formation of the Co(II) complexes with a given phosphine donor decreases as CoL1 > CoL2 > CoL3 > CoL4. The stability of the resulting adducts with different Co(II)-schiff base complexes found to decrease in the order PBu3 > PPh2Me.

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APA: Copy

ASADI, M., MOHAMMADIKISH, M., & MOHAMMADI, K.. (2010). THERMODYNAMIC STUDY OF THE INTERACTION OF CO(II)-SCHIFF BASE COMPLEXES WITH PHOSPHINES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(1), 195-201. SID. https://sid.ir/paper/282442/en

Vancouver: Copy

ASADI M., MOHAMMADIKISH M., MOHAMMADI K.. THERMODYNAMIC STUDY OF THE INTERACTION OF CO(II)-SCHIFF BASE COMPLEXES WITH PHOSPHINES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(1):195-201. Available from: https://sid.ir/paper/282442/en

IEEE: Copy

M. ASADI, M. MOHAMMADIKISH, and K. MOHAMMADI, “THERMODYNAMIC STUDY OF THE INTERACTION OF CO(II)-SCHIFF BASE COMPLEXES WITH PHOSPHINES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 1, pp. 195–201, 2010, [Online]. Available: https://sid.ir/paper/282442/en

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