SYNTHESIS, COMPLEXATION AND USE OF CALIX[4]CROWN-6 AS A NOVEL NEUTRAL IONOPHORE FOR THE PREPARATION OF A SELECTIVE AND SENSITIVE PVC-MEMBRANE POTENTIOMETRIC SENSOR FOR BA2+ ION

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

SAHARI S.; TAGHDIRI M.; ALIZADEH K.; ASFARI Z.; SHAMSIPUR M.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2011 | Volume:8 | Issue:3 Page(s): 879-888

Download Full-Text

View:

302

Download:

134

Cites:

Information Journal Paper

Title

SYNTHESIS, COMPLEXATION AND USE OF CALIX[4]CROWN-6 AS A NOVEL NEUTRAL IONOPHORE FOR THE PREPARATION OF A SELECTIVE AND SENSITIVE PVC-MEMBRANE POTENTIOMETRIC SENSOR FOR BA2+ ION

Author(s)

Keywords

CALIX [4] CROWN-6

COMPLEXATION STUDIES

CONDUCTANCE

BA2+ ION

PVC-MEMBRANE

POTENTIOMETRIC SENSOR

Abstract

Calix[4]crown-6 (L) was synthesized and the stoichiometry and stability of its complexes with alkali, alkaline earth, Ag+, Tl+ and NH4+ions were studied conductometrically in acetonitrile solution. The resulting 1: 1 Ba2+ -L complex was found to be the most stable one among all cation complexes studied. The optimized structures of the ligand and its Ba2+ complex are also reported. Based on the findings, L was used as a suitable ionophore to prepare a PVC-MEMBRANE selective electrode for Ba2+ ion.The electrode revealed a Nernstian behavior over wide barium ion concentration 1.0´10-6 to 1.0´10-3 M with only little trace of 7.1´10-7 M. The potentiometric responses were found to be independent of the pH of test solutions in the range of 4.0-10.0. The proposed electrode response time of about 10 s proved to be highly selective for Ba2+ ion over a wide variety of cations including alkali, alkaline earth, transition and heavy metal ions. The sensor could be used for at least three months without any noticeable deviation. The practical utility of the proposed electrode was also examined.

Cites

No record.

References

No record.

Cite

APA: Copy

SAHARI, S., TAGHDIRI, M., ALIZADEH, K., ASFARI, Z., & SHAMSIPUR, M.. (2011). SYNTHESIS, COMPLEXATION AND USE OF CALIX[4]CROWN-6 AS A NOVEL NEUTRAL IONOPHORE FOR THE PREPARATION OF A SELECTIVE AND SENSITIVE PVC-MEMBRANE POTENTIOMETRIC SENSOR FOR BA²⁺ ION. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 8(3), 879-888. SID. https://sid.ir/paper/282603/en

Vancouver: Copy

SAHARI S., TAGHDIRI M., ALIZADEH K., ASFARI Z., SHAMSIPUR M.. SYNTHESIS, COMPLEXATION AND USE OF CALIX[4]CROWN-6 AS A NOVEL NEUTRAL IONOPHORE FOR THE PREPARATION OF A SELECTIVE AND SENSITIVE PVC-MEMBRANE POTENTIOMETRIC SENSOR FOR BA²⁺ ION. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2011;8(3):879-888. Available from: https://sid.ir/paper/282603/en

IEEE: Copy

S. SAHARI, M. TAGHDIRI, K. ALIZADEH, Z. ASFARI, and M. SHAMSIPUR, “SYNTHESIS, COMPLEXATION AND USE OF CALIX[4]CROWN-6 AS A NOVEL NEUTRAL IONOPHORE FOR THE PREPARATION OF A SELECTIVE AND SENSITIVE PVC-MEMBRANE POTENTIOMETRIC SENSOR FOR BA²⁺ ION,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 8, no. 3, pp. 879–888, 2011, [Online]. Available: https://sid.ir/paper/282603/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops