HIGHLY EFFICIENT EPOXIDATION OF ALKENES WITH SODIUM PERIODATE CATALYZED BY REUSABLE POLYSTYRENE-BOUND RUTHENIUM (III) SALOPHEN

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MOGHADAM M.; MIRKHANI V.; TANGESTANINEJAD S.; MOHAMMADPOOR BALTORK I.; KARGAR H.; SHEIKHSHOAEI I.; HATEFI M.

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2011 | Volume:8 | Issue:4 Page(s): 1019-1029

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Title

HIGHLY EFFICIENT EPOXIDATION OF ALKENES WITH SODIUM PERIODATE CATALYZED BY REUSABLE POLYSTYRENE-BOUND RUTHENIUM (III) SALOPHEN

Author(s)

Keywords

RUTHENIUM (III) SALOPHEN

ALKENE EPOXIDATION

SODIUM PERIODATE

POLYSTYRENE

HETEROGENEOUS CATALYSTS

Abstract

In this paper, highly efficient epoxidation of alkenes catalyzed by ruthenium (III) salophen chloride, [Ru (salophen) Cl], supported on functionalized chloromethylated POLYSTYRENE, PS, is reported. The PS was modified with 1, 4-diaminobenzene, 4- aminophenol and 4-aminothiophenol, and [Ru (salophen) Cl] was attached to the supportsvia axial ligation. The prepared catalysts were used for efficient epoxidation of alkenes with NaIO4 at room temperature. These new heterogenized catalysts were characterized by elemental analysis, FT-IR spectroscopy, scanning electron microscopy and transmission electron microscopy. The HETEROGENEOUS CATALYSTS were reusable in the oxidation reactions and were reused several times.

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APA: Copy

MOGHADAM, M., MIRKHANI, V., TANGESTANINEJAD, S., MOHAMMADPOOR BALTORK, I., KARGAR, H., SHEIKHSHOAEI, I., & HATEFI, M.. (2011). HIGHLY EFFICIENT EPOXIDATION OF ALKENES WITH SODIUM PERIODATE CATALYZED BY REUSABLE POLYSTYRENE-BOUND RUTHENIUM (III) SALOPHEN. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 8(4), 1019-1029. SID. https://sid.ir/paper/282625/en

Vancouver: Copy

MOGHADAM M., MIRKHANI V., TANGESTANINEJAD S., MOHAMMADPOOR BALTORK I., KARGAR H., SHEIKHSHOAEI I., HATEFI M.. HIGHLY EFFICIENT EPOXIDATION OF ALKENES WITH SODIUM PERIODATE CATALYZED BY REUSABLE POLYSTYRENE-BOUND RUTHENIUM (III) SALOPHEN. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2011;8(4):1019-1029. Available from: https://sid.ir/paper/282625/en

IEEE: Copy

M. MOGHADAM, V. MIRKHANI, S. TANGESTANINEJAD, I. MOHAMMADPOOR BALTORK, H. KARGAR, I. SHEIKHSHOAEI, and M. HATEFI, “HIGHLY EFFICIENT EPOXIDATION OF ALKENES WITH SODIUM PERIODATE CATALYZED BY REUSABLE POLYSTYRENE-BOUND RUTHENIUM (III) SALOPHEN,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 8, no. 4, pp. 1019–1029, 2011, [Online]. Available: https://sid.ir/paper/282625/en

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