COBALT (II), NICKEL (II), COPPER (II) AND ZINC (II) COMPLEXES WITH NEW TETRAAZA SCHIFF BASE LIGANDS: SYNTHESIS, CHARACTERIZATION AND THERMODYNAMIC STUDIES

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ASADI M.; ABSALAN G.; ZAMANPOUR A.

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Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2011 | Volume:8 | Issue:4 Page(s): 1073-1081

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Title

COBALT (II), NICKEL (II), COPPER (II) AND ZINC (II) COMPLEXES WITH NEW TETRAAZA SCHIFF BASE LIGANDS: SYNTHESIS, CHARACTERIZATION AND THERMODYNAMIC STUDIES

Author(s)

ASADI M. | ABSALAN G. | ZAMANPOUR A. | Issue Writer Certificate

Keywords

COMPLEXES

FORMATION CONSTANTS

THERMODYNAMIC PARAMETERS

TETRAAZA SCHIFF BASE

Abstract

New COMPLEXES of Co (II), Ni (II), Cu (II) and Zn (II) with four new TETRAAZA SCHIFF BASE ligands, N, N'-bis (2-quinolylmethylidene) -1, 2-ethanediimino (L1), N, N'-bis (2-quinolylmethylidene) -1, 2-propanediimino (L2), N, N'-bis (2-quinolylmethylidene) -1, 3-propanediimino (L3), N, N'-bis (2-quinolylmethylidene) -4-nitro-1, 2-phenylenediimine (L4), were synthesized and characterized by elemental analysis, IR, 1H NMR, and UV-Vis spectroscopy. The thermodynamic FORMATION CONSTANTS of the COMPLEXES were measured spectrophotometrically, at the constant ionic strength 0.1 M (NaClO4), at 25oC in MeOH solvent. The trend of the complex formation of a given metal ion with the ligands was found to be as follows L2>L1>L3> L4 and the trend of a given ligand with the metal ions was Co (II)>Ni (II)>Cu (II)>Zn (II).

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APA: Copy

ASADI, M., ABSALAN, G., & ZAMANPOUR, A.. (2011). COBALT (II), NICKEL (II), COPPER (II) AND ZINC (II) COMPLEXES WITH NEW TETRAAZA SCHIFF BASE LIGANDS: SYNTHESIS, CHARACTERIZATION AND THERMODYNAMIC STUDIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 8(4), 1073-1081. SID. https://sid.ir/paper/282628/en

Vancouver: Copy

ASADI M., ABSALAN G., ZAMANPOUR A.. COBALT (II), NICKEL (II), COPPER (II) AND ZINC (II) COMPLEXES WITH NEW TETRAAZA SCHIFF BASE LIGANDS: SYNTHESIS, CHARACTERIZATION AND THERMODYNAMIC STUDIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2011;8(4):1073-1081. Available from: https://sid.ir/paper/282628/en

IEEE: Copy

M. ASADI, G. ABSALAN, and A. ZAMANPOUR, “COBALT (II), NICKEL (II), COPPER (II) AND ZINC (II) COMPLEXES WITH NEW TETRAAZA SCHIFF BASE LIGANDS: SYNTHESIS, CHARACTERIZATION AND THERMODYNAMIC STUDIES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 8, no. 4, pp. 1073–1081, 2011, [Online]. Available: https://sid.ir/paper/282628/en

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