COOPERATIVITY OF CH/π AND HYDROGEN BOND INTERACTIONS IN HF···PY⊥X1BEN X2 COMPLEXES

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KARIMI POUYA; EBRAHIMI ALI; BAZZI SOPHIA

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Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2012 | Volume:9 | Issue:6 Page(s): 991-998

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Title

COOPERATIVITY OF CH/π AND HYDROGEN BOND INTERACTIONS IN HF···PY⊥X1BEN X2 COMPLEXES

Author(s)

KARIMI POUYA | EBRAHIMI ALI | BAZZI SOPHIA

Keywords

T-SHAPED INTERACTION

HYDROGEN BONDING

COOPERATIVITY

HAMMETT CONSTANT

POPULATION ANALYSIS

PYRIDINE

BENZENE

Abstract

A COOPERATIVITY is observed between CH/p and hydrogen bond interactions in HF···Py^X1benX2 complexes. The COOPERATIVITY is more influenced by the inductive effects in comparison with the resonance effects. Increase in the electron withdrawing nature of substituents is accompanied by decrease in the COOPERATIVITY energy (Ecoop). The vital effect of the reactivity centre on the Ecoop is determined through the good relationship between spara+ (the substituted constant estimated for the para placed reactivity center) and Ecoop values.

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APA: Copy

KARIMI, POUYA, EBRAHIMI, ALI, & BAZZI, SOPHIA. (2012). COOPERATIVITY OF CH/π AND HYDROGEN BOND INTERACTIONS IN HF···PY⊥X₁BEN X₂ COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 9(6), 991-998. SID. https://sid.ir/paper/282828/en

Vancouver: Copy

KARIMI POUYA, EBRAHIMI ALI, BAZZI SOPHIA. COOPERATIVITY OF CH/π AND HYDROGEN BOND INTERACTIONS IN HF···PY⊥X₁BEN X₂ COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2012;9(6):991-998. Available from: https://sid.ir/paper/282828/en

IEEE: Copy

POUYA KARIMI, ALI EBRAHIMI, and SOPHIA BAZZI, “COOPERATIVITY OF CH/π AND HYDROGEN BOND INTERACTIONS IN HF···PY⊥X₁BEN X₂ COMPLEXES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 9, no. 6, pp. 991–998, 2012, [Online]. Available: https://sid.ir/paper/282828/en

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