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Information Journal Paper

Title

SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF NEW ZINC (II) AND NICKEL (II) COMPLEXES CONTAINING MORPHOLINE MOIETY AND THEIR ANTIBACTERIAL STUDIES

Pages

  113-119

Keywords

ZINC (II) COMPLEX 
NICKEL (II) COMPLEX 

Abstract

 The ligand 1, 2-dimorpholinoethane (DME) was used to prepare Zn (II) and Ni (II) complexes of the general formulation MLX2 (L=DME, X=Cl or NO3). Zinc (II) complex exhibits spectral properties indicative of a distorted tetrahedral geometry, with DME coordinating through two nitrogen atoms and two chlorides completing the tetrahedron. This is in contrast to the six-coordinated, distorted octahedral geometry exhibited by nickel (II) complex of DME when NO3 was used as counter ions. The X-ray diffraction confirms the structures of two complexes and shows that the ligand coordinates through two nitrogen atoms while the two ether linkages are not involved in complexation, which would have been the case if the morpholine rings were in the boat form. The ligand and related complexes have antibacterial activity against the five Gram-positive bacteria: Bacillus subtilis ATCC 6633, Staphylococcus aureus ATCC 6538, Bacillus cereus NRRL-B-3711, Enterococcus faecalis ATCC 29212 and Streptococcus pyogenes and also against the three Gram-negative bacteria: Escherichia coli ATCC 11230, Pseudomonas aeruginosa ATCC 15442 and Klebsiella pneumonia ATCC 70063. The results showed that in some cases the antibacterial activity of the complexes exceeded the one of sulfisoxazole used as a standard.

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    APA: Copy

    GOUDARZIAFSHAR, HAMID, REZAEIVALA, MAJID, KHOSRAVI, FAYEZEH, ABBASITYULA, YUNES, YOUSEFI, SOMAIEH, OZBEK, NESLIHAN, EIGNER, VACLAV, & DUSEK, MICHAL. (2015). SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF NEW ZINC (II) AND NICKEL (II) COMPLEXES CONTAINING MORPHOLINE MOIETY AND THEIR ANTIBACTERIAL STUDIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 12(1), 113-119. SID. https://sid.ir/paper/283032/en

    Vancouver: Copy

    GOUDARZIAFSHAR HAMID, REZAEIVALA MAJID, KHOSRAVI FAYEZEH, ABBASITYULA YUNES, YOUSEFI SOMAIEH, OZBEK NESLIHAN, EIGNER VACLAV, DUSEK MICHAL. SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF NEW ZINC (II) AND NICKEL (II) COMPLEXES CONTAINING MORPHOLINE MOIETY AND THEIR ANTIBACTERIAL STUDIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2015;12(1):113-119. Available from: https://sid.ir/paper/283032/en

    IEEE: Copy

    HAMID GOUDARZIAFSHAR, MAJID REZAEIVALA, FAYEZEH KHOSRAVI, YUNES ABBASITYULA, SOMAIEH YOUSEFI, NESLIHAN OZBEK, VACLAV EIGNER, and MICHAL DUSEK, “SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF NEW ZINC (II) AND NICKEL (II) COMPLEXES CONTAINING MORPHOLINE MOIETY AND THEIR ANTIBACTERIAL STUDIES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 12, no. 1, pp. 113–119, 2015, [Online]. Available: https://sid.ir/paper/283032/en

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    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
    مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources
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