PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES OF A NOVEL LANTHANIDE TETRA (4-SULFONATOPHENYL) PORPHYRIN

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CHEN WEN TONG; HU RONG HUA; XU YA PING; LUO QIU YAN; DAI YAN KANG; HUANG SHAN LIN; GUO PEI YU

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2015 | Volume:12 | Issue:6 Page(s): 937-942

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Title

PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES OF A NOVEL LANTHANIDE TETRA (4-SULFONATOPHENYL) PORPHYRIN

Author(s)

Keywords

CRYSTAL

OPEN FRAMEWORK

PHOTOLUMINESCENCE

PORPHYRIN

TERBIUM

Abstract

A novel lanthanide PORPHYRIN [TbIII (H2TPPS) IV.H3O.2H2O] n (1) (H2TPPS = tetra (4-sulfonatophenyl) PORPHYRIN) has been synthesized through a hydrothermal reaction and structurally characterized by single-CRYSTAL X-ray diffraction. Complex 1 is characterized by a three-dimensional porous OPEN FRAMEWORK with the TERBIUM atom coordinated by eight oxygen atoms to yield a distorted square anti-prism. TG-DTA measurements reveal that complex 1 is thermally stable up to 400 oC. PHOTOLUMINESCENCE investigations show that complex 1 has an emission in the red region with a quantum yield of 1.7 % and a lifetime of 341 ms. CV-DPV studies discover one reductive potential of -0.36 V and one quasi-reversible wave with E 1/2=-0.82 V.

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APA: Copy

CHEN, WEN TONG, HU, RONG HUA, XU, YA PING, LUO, QIU YAN, DAI, YAN KANG, HUANG, SHAN LIN, & GUO, PEI YU. (2015). PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES OF A NOVEL LANTHANIDE TETRA (4-SULFONATOPHENYL) PORPHYRIN. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 12(6), 937-942. SID. https://sid.ir/paper/283097/en

Vancouver: Copy

CHEN WEN TONG, HU RONG HUA, XU YA PING, LUO QIU YAN, DAI YAN KANG, HUANG SHAN LIN, GUO PEI YU. PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES OF A NOVEL LANTHANIDE TETRA (4-SULFONATOPHENYL) PORPHYRIN. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2015;12(6):937-942. Available from: https://sid.ir/paper/283097/en

IEEE: Copy

WEN TONG CHEN, RONG HUA HU, YA PING XU, QIU YAN LUO, YAN KANG DAI, SHAN LIN HUANG, and PEI YU GUO, “PHOTOPHYSICAL AND ELECTROCHEMICAL PROPERTIES OF A NOVEL LANTHANIDE TETRA (4-SULFONATOPHENYL) PORPHYRIN,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 12, no. 6, pp. 937–942, 2015, [Online]. Available: https://sid.ir/paper/283097/en

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