HETEROGENEOUS OXIDATION OF ALCOHOLS WITH HYDROGEN PEROXIDE CATALYZED BY POLYOXOMETALATE METAL–ORGANIC FRAMEWORK

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KAZEMI BABAHYDARI ALI; FAREGHI ALAMDARI REZA; MORADPOUR HAFSHEJANI SHAHRBANOU; AMIRI RUDBARI HADI; RIAHI FARSANI MOSTAFA

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2016 | Volume:13 | Issue:8 Page(s): 0-0

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Title

HETEROGENEOUS OXIDATION OF ALCOHOLS WITH HYDROGEN PEROXIDE CATALYZED BY POLYOXOMETALATE METAL–ORGANIC FRAMEWORK

Author(s)

Keywords

ALCOHOLS HETEROGENEOUS CATALYSIS MOF POLYOXOMETALATESH2O2

Abstract

HSiW-MOF, PMo-MOF, HPMo-MOF and PW-MOF were synthesized and characterized by elemental analysis, UV–Vis, FT-IR, cyclic voltammetry and XRD. These compounds were used as catalyst for the selective oxidation of alcohols by hydrogen peroxide. Within them, PW-MOF showed a higher catalytic activity compared to other catalysts in a similar reaction condition. Therefore, PW-MOF catalyst system was successfully used for the selective oxidation of the benzylic, linear and secondary alcohols to the corresponding aldehydes and ketones. Also, allylic alcohols were converted to the corresponding aldehydes with high conversion and significant selectivity. Moreover, PW-MOF was stable to leaching, behaved as true heterogeneous catalysts, easily recovered by filtration, and reused four times with the preserve of the catalytic performance.

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APA: Copy

KAZEMI BABAHYDARI, ALI, FAREGHI ALAMDARI, REZA, MORADPOUR HAFSHEJANI, SHAHRBANOU, AMIRI RUDBARI, HADI, & RIAHI FARSANI, MOSTAFA. (2016). HETEROGENEOUS OXIDATION OF ALCOHOLS WITH HYDROGEN PEROXIDE CATALYZED BY POLYOXOMETALATE METAL–ORGANIC FRAMEWORK. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 13(8), 0-0. SID. https://sid.ir/paper/283193/en

Vancouver: Copy

KAZEMI BABAHYDARI ALI, FAREGHI ALAMDARI REZA, MORADPOUR HAFSHEJANI SHAHRBANOU, AMIRI RUDBARI HADI, RIAHI FARSANI MOSTAFA. HETEROGENEOUS OXIDATION OF ALCOHOLS WITH HYDROGEN PEROXIDE CATALYZED BY POLYOXOMETALATE METAL–ORGANIC FRAMEWORK. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2016;13(8):0-0. Available from: https://sid.ir/paper/283193/en

IEEE: Copy

ALI KAZEMI BABAHYDARI, REZA FAREGHI ALAMDARI, SHAHRBANOU MORADPOUR HAFSHEJANI, HADI AMIRI RUDBARI, and MOSTAFA RIAHI FARSANI, “HETEROGENEOUS OXIDATION OF ALCOHOLS WITH HYDROGEN PEROXIDE CATALYZED BY POLYOXOMETALATE METAL–ORGANIC FRAMEWORK,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 13, no. 8, pp. 0–0, 2016, [Online]. Available: https://sid.ir/paper/283193/en

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