مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

video

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

sound

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Persian Version

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View:

384
مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Download:

157
مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Cites:

Information Journal Paper

Title

Influence of calcination temperature on the activity of mesoporous CaO/TiO2– ZrO2 catalyst in the esterification reaction

Pages

  321-331

Abstract

 In the present study, the effect of Calcination temperature on the structure and performance of mesoporous CaO/TiO2– ZrO2 catalyst fabricated by sol– gel method used in the esterification reaction was assessed. Then, CaO/TiO2 catalyst was also synthesized via the same method to evaluate the effect of Zirconia cations on its properties and activity. The samples were characterized by X-ray Diffraction (XRD), Fourier transmittance infra-red (FT-IR), Brunauer– Emmett– Teller (BET)– Barrett-Joyner-Halenda (BJH), scanning electron microscope (SEM) and transmission electron microscopy (TEM) analyses. Moreover, Hammett indicator method was utilized to assess the acidity and basicity of the samples. It was found that zirconium was clearly incorporated in CaO/TiO2 lattice and transformed that from amorphous phase to crystalline structure. In addition, the basicity and acidity of CaO/TiO2 was clearly increased by Zirconia loading. Evaluation of the samples’ activity presented that CaO/TiO2 catalyst exhibit no activity in the esterification reaction, while all CaO/TiO2– ZrO2 catalysts showed high ability to convert oleic acid to its ester. Moreover, the catalyst calcined at 400 ° C showed the highest activity in the esterification reaction with desirable properties such as high crystallinity, acidity, basicity and surface area along with well-distribution of particle size and pore size. The best catalyst converted around 90% of oleic acid to ester at optimized conditions of 150 ° C, 12: 1 molar ratio of methanol/oleic acid, 3 wt% of catalyst for 4 h of reaction time. Moreover, the sample was successfully used for five runs without significant reduction in activity that makes it a suitable choice as a catalyst for industrial applications.

Cites

  • No record.

    • References

  • No record.

    • Cite

    APA: Copy

    Sistani, Aliakbar, Saghatoleslami, Naser, & Nayebzadeh, Hamed. (2018). Influence of calcination temperature on the activity of mesoporous CaO/TiO2– ZrO2 catalyst in the esterification reaction. JOURNAL OF NANOSTRUCTURE IN CHEMISTRY, 8(3), 321-331. SID. https://sid.ir/paper/333342/en

    Vancouver: Copy

    Sistani Aliakbar, Saghatoleslami Naser, Nayebzadeh Hamed. Influence of calcination temperature on the activity of mesoporous CaO/TiO2– ZrO2 catalyst in the esterification reaction. JOURNAL OF NANOSTRUCTURE IN CHEMISTRY[Internet]. 2018;8(3):321-331. Available from: https://sid.ir/paper/333342/en

    IEEE: Copy

    Aliakbar Sistani, Naser Saghatoleslami, and Hamed Nayebzadeh, “Influence of calcination temperature on the activity of mesoporous CaO/TiO2– ZrO2 catalyst in the esterification reaction,” JOURNAL OF NANOSTRUCTURE IN CHEMISTRY, vol. 8, no. 3, pp. 321–331, 2018, [Online]. Available: https://sid.ir/paper/333342/en

    Related Journal Papers

  • No record.

    • Related Seminar Papers

  • No record.

    • Related Plans

  • No record.

    • Recommended Workshops






    Move to top
    telegram sharing button
    whatsapp sharing button
    linkedin sharing button
    twitter sharing button
    email sharing button
    email sharing button
    email sharing button
    sharethis sharing button