Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium(IV) Complexe: trans-[Pt(4-mpy)2Cl4]

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Faal Hamedani Naghmeh; AMANI VAHID

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Journal: Applied Chemistry Today Year:2020 | Volume:14 | Issue:53 Page(s): 79-84

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Title

Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium(IV) Complexe: trans-[Pt(4-mpy)2Cl4]

Author(s)

Faal Hamedani Naghmeh | AMANI VAHID | Issue Writer Certificate

Keywords

crystal structureQ2

platinum(IV) complexQ1

4-methylpyridineQ1

luminescent propertiesQ1

Abstract

The new trans-[Pt(4-mpy)2Cl4] (1) complex (4-mpy is 4-methylpyridine) was prepared from the reaction of H2PtCl6. 6H2O with 4-methylpyridine in methanol. The synthesized complex was thoroughly characterized by elemental analysis, IR, 1H-NMR, 13C{1H}-NMR and 195Pt-NMR spectroscopy. Elemental analysis data (C, H, N) support the general composition of the complex 1 and the structure has been established by single-crystal X-ray diffraction study. In this complex, the geometry platinum(IV) cation is octahedral, formed by two nitrogen atoms from two 4-mpy ligands and four chloride anions. Also, in this complex, the strong π … π interactions between the pyridine rings are effective on the stabilization of the crystal packing. Furthermore, the luminescence properties of the free 4-mpy ligand as well as the complex 1 were investigated in solution. Luminescence emission of complex 1 was red shifted compared to the free 4-mpy ligand in dimethyl sulfoxide solution.

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APA: Copy

Faal Hamedani, Naghmeh, & AMANI, VAHID. (2020). Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium(IV) Complexe: trans-[Pt(4-mpy)2Cl4]. JOURNAL OF APPLIED CHEMISTRY, 14(53 ), 79-84. SID. https://sid.ir/paper/379470/en

Vancouver: Copy

Faal Hamedani Naghmeh, AMANI VAHID. Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium(IV) Complexe: trans-[Pt(4-mpy)2Cl4]. JOURNAL OF APPLIED CHEMISTRY[Internet]. 2020;14(53 ):79-84. Available from: https://sid.ir/paper/379470/en

IEEE: Copy

Naghmeh Faal Hamedani, and VAHID AMANI, “Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium(IV) Complexe: trans-[Pt(4-mpy)2Cl4],” JOURNAL OF APPLIED CHEMISTRY, vol. 14, no. 53 , pp. 79–84, 2020, [Online]. Available: https://sid.ir/paper/379470/en

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