Experimental and theoretical study of interactions between a ketone and a series of 2-alkanol using Kirkwood-Buff method

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

Shahbazi Elham; ALMASI MOHAMMAD

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Applied Chemistry Today Year:2020 | Volume:15 | Issue:55 Page(s): 25-36

Download Full-Text

Persian Verion

View:

304

Download:

Cites:

Information Journal Paper

Title

Experimental and theoretical study of interactions between a ketone and a series of 2-alkanol using Kirkwood-Buff method

Author(s)

Shahbazi Elham | ALMASI MOHAMMAD | Issue Writer Certificate

Keywords

Methyl ethyl ketoneQ1

second-order alcoholsQ1

Kirkwood-Buff integralsQ1

molecular interactionsQ1

Abstract

In this paper, the interaction between Methyl ethyl ketone and some types of alcohols (2-propanol, 2-butanol, 2-pentanol, 2-hexanol and 2-heptanolol) was studied using an empirical method along with Kirkwood-Buff integrals and the of preferential solvation phenomenon. For binary systems including Methyl ethyl ketone with 2-alkanol, the parameters Gii, Gjj, Gij, δ ii, δ jj, and δ ij were calculated at 298. 18 K and interpreted based on the structure and type of bond formed in solutions. The results were discussed based on molecular interactions and the effect of carbon chain lengths of alcohol. In general, it can be concluded that the interactions in the mixtures are weaker than the pure state, and with the increase in the length of the alcohol chain, these interactions become weaker because, as the chain length increases, the nonpolar part of the molecule increases. The results obtained from the Kirkwood-Buff integrals were confirmed using experimental values of excess molar volumes.

Cites

No record.

References

No record.

Cite

APA: Copy

Shahbazi, Elham, & ALMASI, MOHAMMAD. (2020). Experimental and theoretical study of interactions between a ketone and a series of 2-alkanol using Kirkwood-Buff method. JOURNAL OF APPLIED CHEMISTRY, 15(55 ), 25-36. SID. https://sid.ir/paper/404610/en

Vancouver: Copy

Shahbazi Elham, ALMASI MOHAMMAD. Experimental and theoretical study of interactions between a ketone and a series of 2-alkanol using Kirkwood-Buff method. JOURNAL OF APPLIED CHEMISTRY[Internet]. 2020;15(55 ):25-36. Available from: https://sid.ir/paper/404610/en

IEEE: Copy

Elham Shahbazi, and MOHAMMAD ALMASI, “Experimental and theoretical study of interactions between a ketone and a series of 2-alkanol using Kirkwood-Buff method,” JOURNAL OF APPLIED CHEMISTRY, vol. 15, no. 55 , pp. 25–36, 2020, [Online]. Available: https://sid.ir/paper/404610/en

Related Journal Papers