The Synthesis of Allylic Esters via Direct Allylic C– H Bonds Oxidation of Cycloolefins in the Presence of Copper Oxide Nanoparticles and Nanoporous Silica

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SAMADI SAADI; Samadi Mojgan

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Journal: Nashrieh Shimi va Mohandesi Shimi Iran Year:2020 | Volume:38 | Issue:4 (94) Page(s): 53-64

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Information Journal Paper

Title

The Synthesis of Allylic Esters via Direct Allylic C– H Bonds Oxidation of Cycloolefins in the Presence of Copper Oxide Nanoparticles and Nanoporous Silica

Author(s)

SAMADI SAADI | Samadi Mojgan | Issue Writer Certificate

Keywords

CuO nanoparticlesQ1

Allylic oxidationQ1

C–H bond activationQ1

CycloolefinsQ1

Nanoporous SilicaQ1

Allylic esterQ1

Abstract

Copper Oxide(CuO) nanoparticles and Nanoporous Silica such as MCM-41 and SBA-15 were synthesized and characterized by Fourier Transform InfraRed (FT-IR) spectroscopy, X-Ray Diffraction (XRD), and Sscanning Electron Microscopy (SEM). The synthesized copper oxide nanocatalyst was applied in Allylic oxidation of Cycloolefinsvia C– H bonds activation by tert-butyl-p-nitrobenzoperoxoate as oxidant and in the presence of Nanoporous Silica as additive. Allylic esters were obtained in good yields (up to 90%) and reasonable reaction times. Also, the recovered catalyst was applicable in the Allylic oxidation reaction for four times without loss in catalytic reactivity and yield. The structure of tert-butyl-p-nitrobenzoperoxoate and Allylic esters were characterized by 1HNMR, and 13CNMR spectroscopy.

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APA: Copy

SAMADI, SAADI, & Samadi, Mojgan. (2020). The Synthesis of Allylic Esters via Direct Allylic C– H Bonds Oxidation of Cycloolefins in the Presence of Copper Oxide Nanoparticles and Nanoporous Silica. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 38(4 (94) ), 53-64. SID. https://sid.ir/paper/408903/en

Vancouver: Copy

SAMADI SAADI, Samadi Mojgan. The Synthesis of Allylic Esters via Direct Allylic C– H Bonds Oxidation of Cycloolefins in the Presence of Copper Oxide Nanoparticles and Nanoporous Silica. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2020;38(4 (94) ):53-64. Available from: https://sid.ir/paper/408903/en

IEEE: Copy

SAADI SAMADI, and Mojgan Samadi, “The Synthesis of Allylic Esters via Direct Allylic C– H Bonds Oxidation of Cycloolefins in the Presence of Copper Oxide Nanoparticles and Nanoporous Silica,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 38, no. 4 (94) , pp. 53–64, 2020, [Online]. Available: https://sid.ir/paper/408903/en

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