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Information Journal Paper

Title

CRYSTAL STRUCTURE OF BIS (2,6-DIAMINOPYRIDINIUM) TETRACHLORO PALLADATE(II) OF A PYRIDINE CONTAINING SELF- ASSEMBLING SYSTEM

Pages

  197-205

Keywords

Not Registered.

Abstract

 The reaction between LH2, [pyda.H2] [pydc], (pyda = 2, 6 - pyridinediamine and pydc. H2 = 2, 6 - pyridinedicarboxylic acid), ligand with palladium (II) chloride leads to the formation of  [pyda.H]2 [PdCI4]. The crystal structure of the compound was determined by X-ray diffraction. The crystal system is triclinic with space group Pī and one molecule per unit cell. The unit cell dimensions are a = 6.900(3) Ǻ, b = 7.898(3) Ǻ, c = 8.025 (3) Ǻ, with α = 103.302(14) °, β = 104.068(14)° and γ= 92.415(12)°.The final R value is 0.0602 for 1988 reflections. The  resumably of the formation [pyda.H][Pd(pydc)(pydc.H)], [Pd(pydc.H)2] and [pyda.H]CI species, was studied by IR, ESI/MS, 1H NMR, 13C NMR spectroscopy, and elemental analysis.  

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  • Cite

    APA: Copy

    RANJBAR, M., AGHABOZORG, H., & MOGHIMI, A.. (2002). CRYSTAL STRUCTURE OF BIS (2,6-DIAMINOPYRIDINIUM) TETRACHLORO PALLADATE(II) OF A PYRIDINE CONTAINING SELF- ASSEMBLING SYSTEM. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, 10(2), 197-205. SID. https://sid.ir/paper/4157/en

    Vancouver: Copy

    RANJBAR M., AGHABOZORG H., MOGHIMI A.. CRYSTAL STRUCTURE OF BIS (2,6-DIAMINOPYRIDINIUM) TETRACHLORO PALLADATE(II) OF A PYRIDINE CONTAINING SELF- ASSEMBLING SYSTEM. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY[Internet]. 2002;10(2):197-205. Available from: https://sid.ir/paper/4157/en

    IEEE: Copy

    M. RANJBAR, H. AGHABOZORG, and A. MOGHIMI, “CRYSTAL STRUCTURE OF BIS (2,6-DIAMINOPYRIDINIUM) TETRACHLORO PALLADATE(II) OF A PYRIDINE CONTAINING SELF- ASSEMBLING SYSTEM,” IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, vol. 10, no. 2, pp. 197–205, 2002, [Online]. Available: https://sid.ir/paper/4157/en

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