CRYSTAL STRUCTURE OF (2,2'-BIPYRIDINE) (2,5-DICHLOROPHENYLCYANAMIDO) (2,2':6',2

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AMIRI S.; HADADZADEH H.; REZVANI A.R.

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Journal: Iranian Journal of Crystallography and Mineralogy Year:2006 | Volume:13 | Issue:2 Page(s): 389-398

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Title

CRYSTAL STRUCTURE OF (2,2'-BIPYRIDINE) (2,5-DICHLOROPHENYLCYANAMIDO) (2,2':6',2"- TERPYRIDINE) RHODIUM(III) HEXAFLUOROPHOSPHATE, [RH (TERPY) (BPY) (2,5-CL2PCYD)] (PF6)2.0.5CH3CN

Author(s)

AMIRI S. | HADADZADEH H. | REZVANI A.R. | Issue Writer Certificate

Keywords

PHENYLCYANAMIDE LIGANDSQ4

RHODIUM (III) COMPLEXQ4

PYRIDYL RINGQ4

BIPYRIDINEQ3

TERPYRIDINEQ4

Abstract

The first crystal structure of a phenylcyanamide Rh (III) complex, [Rh (terpy) (bpy) (2,5-Cl2pcyd)] (PF6)2 (terpy = 2,2':6',2"- TERPYRIDINE, bpy= 2,2' -bipyridine, and 2,5-Cl2pcyd = 2,5-dichlorophenylcyanamide) has been reported in this paper. Crystals of [Rh (terpy) (bpy) (2,5-Cl2pcyd)] (PF6)2 .0.5CH3CN were grown by ether diffusion into an acetonitrile solution of the complex. Crystal structure data: orthorhombic system, space group Fdd2, with a = 84.228(3), b = 8.7162(3), c = 21.4921(7)Å, V=15778.4(9) Å3, and Z=16. The structure was refined by using 4971 independent reflections with I>2σ(I) to a R factor of 0.0644 and Rw= 0.1752. ORTEP drawing of [Rh (terpy) (bpy) (2,5-Cl2pcyd)] (PF6)2 .0.5CH3CN shows that the terpy and bpy ligands are coordinated to the RhIII through their nitrogen atoms in a mutually perpendicular fashion. The anionic cyanamide group is coordinated end-on by the nitrile nitrogen to the RhIII. The RhIII-NCN bond is bent, having an angle of 125.4°. This bent bond is largely determined by the σ-bonding interaction of a cyanamide non-bonding electron pair in a Sp2 hybrid orbital.

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APA: Copy

AMIRI, S., HADADZADEH, H., & REZVANI, A.R.. (2006). CRYSTAL STRUCTURE OF (2,2'-BIPYRIDINE) (2,5-DICHLOROPHENYLCYANAMIDO) (2,2':6',2"- TERPYRIDINE) RHODIUM(III) HEXAFLUOROPHOSPHATE, [RH (TERPY) (BPY) (2,5-CL2PCYD)] (PF6)2.0.5CH3CN. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, 13(2), 389-398. SID. https://sid.ir/paper/4211/en

Vancouver: Copy

AMIRI S., HADADZADEH H., REZVANI A.R.. CRYSTAL STRUCTURE OF (2,2'-BIPYRIDINE) (2,5-DICHLOROPHENYLCYANAMIDO) (2,2':6',2"- TERPYRIDINE) RHODIUM(III) HEXAFLUOROPHOSPHATE, [RH (TERPY) (BPY) (2,5-CL2PCYD)] (PF6)2.0.5CH3CN. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY[Internet]. 2006;13(2):389-398. Available from: https://sid.ir/paper/4211/en

IEEE: Copy

S. AMIRI, H. HADADZADEH, and A.R. REZVANI, “CRYSTAL STRUCTURE OF (2,2'-BIPYRIDINE) (2,5-DICHLOROPHENYLCYANAMIDO) (2,2':6',2"- TERPYRIDINE) RHODIUM(III) HEXAFLUOROPHOSPHATE, [RH (TERPY) (BPY) (2,5-CL2PCYD)] (PF6)2.0.5CH3CN,” IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, vol. 13, no. 2, pp. 389–398, 2006, [Online]. Available: https://sid.ir/paper/4211/en

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