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Title

SYNTHESIS, CHARACTERIZATION, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL PROPERTIES OF RUTHENIUM(II) COMPLEXES CONTAINING PHENYLCYANAMIDE LIGANDS AND EFFECT OF THE INNER- SPHERE ON THE RU-NCN CHROMOPHORE

Pages

  21-30

Keywords

RUTHENIUM (II) COMPLEX 

Abstract

 [Ru(terpy)(bpy)(L)]PF6 complexes, where terpy is 2,2":6",2"- terpyridine, bpy is 2,2" - bipyridine and L is monoanions of 4 - bromophenylcyanamide (4 - Brpcyd), 4-methoxyphenylcyanamide (4 - MeOPcyd), 2, 4 - dibromophenylcyanamide (2,4 - Br2pcyd), 2,4-dimethylphenylcyanamide (2,4 - Me2pcyd), 2 - methylphenylcyanamide (2 - MePcyd), PHENYLCYANAMIDE (Pcyd) and naphtylcyanamide (ncyd) have been prepared and characterized by elemental analysis, IR, 1H-NMR and UV-vis spectroscopies and cyclic voltammetry. Spectroelectrochemistry was used to generate the electronic absorption spectra of the Ru(III) complexes, [Ru(terpy)(bpy)(L)]2+ in acetonitrile solution. The spectral data associated with the Ru(III)-cyanamido LMCT chromophore were compared to those derived from Ru(III) analogues in order to gain a greater understanding the effect of spectator ligands on the nature of the Ru(III)-Cyanamide bond. The data supports greater covalency in the Ru(III)-cyanamide bond of [Ru(terpy)(bpy)(L)]2+ complexes compared to their Ru(III) analogues.

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    APA: Copy

    HADADZADEH, H., & REZVANI, A.R.. (2005). SYNTHESIS, CHARACTERIZATION, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL PROPERTIES OF RUTHENIUM(II) COMPLEXES CONTAINING PHENYLCYANAMIDE LIGANDS AND EFFECT OF THE INNER- SPHERE ON THE RU-NCN CHROMOPHORE. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 24(2), 21-30. SID. https://sid.ir/paper/528215/en

    Vancouver: Copy

    HADADZADEH H., REZVANI A.R.. SYNTHESIS, CHARACTERIZATION, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL PROPERTIES OF RUTHENIUM(II) COMPLEXES CONTAINING PHENYLCYANAMIDE LIGANDS AND EFFECT OF THE INNER- SPHERE ON THE RU-NCN CHROMOPHORE. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2005;24(2):21-30. Available from: https://sid.ir/paper/528215/en

    IEEE: Copy

    H. HADADZADEH, and A.R. REZVANI, “SYNTHESIS, CHARACTERIZATION, ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL PROPERTIES OF RUTHENIUM(II) COMPLEXES CONTAINING PHENYLCYANAMIDE LIGANDS AND EFFECT OF THE INNER- SPHERE ON THE RU-NCN CHROMOPHORE,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 24, no. 2, pp. 21–30, 2005, [Online]. Available: https://sid.ir/paper/528215/en

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