SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN TCNQ AND CRYPTAND 222 IN CHLOROFORM SOLUTION

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POURETEDAL H.R.; SEMNANI A.

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ISSN: 2588-4824

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Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2005 | Volume:24 | Issue:3 Page(s): 53-57

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Title

SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN TCNQ AND CRYPTAND 222 IN CHLOROFORM SOLUTION

Author(s)

POURETEDAL H.R. | SEMNANI A. | Issue Writer Certificate

Keywords

C222

TCNQ

SPECTROPHOTOMETRY

MOLECULAR COMPLEX

CHLOROFORM

Abstract

The interaction between 4, 7, 13, 16, 21, 24 - hexaoxa-1,10 - diazabicyclo [8.8.8] hexacosane (C222) and 7,7,8,8- teracyanoquinodimethane (TCNQ) has been studied in CHLOROFORM at 25°C. The results indicate a two step mechanism. At the first step, two adducts (assign as P1 and P2) are formed through equilibrium reactions. In continue and through nonequilibrium reactions the adducts are converted to a final product (assign as P3). Based on the comparison of the spectra of C222-TCNQ mixture with that of Na-18C6-TCNQ mixture, the C222+TCNQ-, C222+TCNQ¯ TCNQo and (C222+)2(TCNQ-)2 are suggested as the P1, P2, and P3, respectively. IR specra of C222 and TCNQ are compared with the spectrum of solid 1:1 TCNQ-C222 complex and the effect of complexation on absorption bands is discussed.

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APA: Copy

POURETEDAL, H.R., & SEMNANI, A.. (2005). SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN TCNQ AND CRYPTAND 222 IN CHLOROFORM SOLUTION. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 24(3), 53-57. SID. https://sid.ir/paper/529696/en

Vancouver: Copy

POURETEDAL H.R., SEMNANI A.. SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN TCNQ AND CRYPTAND 222 IN CHLOROFORM SOLUTION. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2005;24(3):53-57. Available from: https://sid.ir/paper/529696/en

IEEE: Copy

H.R. POURETEDAL, and A. SEMNANI, “SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN TCNQ AND CRYPTAND 222 IN CHLOROFORM SOLUTION,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 24, no. 3, pp. 53–57, 2005, [Online]. Available: https://sid.ir/paper/529696/en

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