PREPARATION OF DIBLOCK AND TRIBLOCK COPOLYMERS OF STYRENE, 2,5-NORBORNADIENE, ETHYLMETHACRYLATE AND PEG BY NITROXIDE-CONTROLLED FREE RADICAL POLYMERIZATION

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

ADELI M.; ENTEZAMI A.A.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Iranian Polymer Journal Year:2001 | Volume:10 | Issue:6 Page(s): 393-402

Download Full-Text

View:

408

Download:

247

Cites:

Information Journal Paper

Title

PREPARATION OF DIBLOCK AND TRIBLOCK COPOLYMERS OF STYRENE, 2,5-NORBORNADIENE, ETHYLMETHACRYLATE AND PEG BY NITROXIDE-CONTROLLED FREE RADICAL POLYMERIZATION

Author(s)

ADELI M. | ENTEZAMI A.A. | Issue Writer Certificate

Keywords

DIBLOCK AND TRIBLOCK COPOLYMER

SYNTHESIS

5-NORBORNADIENE

POLYSTYRENE-TEMPO

LIVING RADICAL POLYMERIZATION

Abstract

2,5-NORBORNADIENE has been polymerized in bulk at 125 °C in presence of a low molar mass of POLYSTYRENE-TEMPO as macroinitiator. The structure and poly-dispersity of the obtained diblock copolymer (PSt-PNB-TEMPO) were determined by IR,1 H NMR spectroscopy and GPC measurement, respectively, where TEMPO is 2,2,6,6 tetramethylpiperidinyl-1-oxy and PNB is polynorbornadiene. The triblock copolymer of styrene-2,5-NORBORNADIENE-ethylmethacrylate (PSt-PNB-PEMA) using a PSt-PNB-TEMPO as the macroinitiator in the presence of camphorsulphonic acid (CSA) was prepared. Also the triblock. copolymer containing polyethylmethacrylate and poly(ethylene glycol) designated as PEMA-PEG-PEMA was synthesized by a novel method. The 1H NMR and FTIR studies of triblock copolymers confirmed their structures and the absence of TEMPO end groups for PEMA.

Cites

No record.

References

No record.

Cite

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops