INFLUENCE OF NITROGEN BASES ON EPOXIDATION OF CYCLOOCTENE WITH SODIUM PERIODATE CATALYSED BY MANGANESE(III) PORPHYRINS

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MOHAJER D.; TAYEBEE R.

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Journal Paper

Paper Information

Journal: Iranian Journal of Chemistry and Chemical Engineering Year:1999 | Volume:18 | Issue:1 Page(s): 27-29

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Information Journal Paper

Title

INFLUENCE OF NITROGEN BASES ON EPOXIDATION OF CYCLOOCTENE WITH SODIUM PERIODATE CATALYSED BY MANGANESE(III) PORPHYRINS

Author(s)

MOHAJER D. | TAYEBEE R. | Issue Writer Certificate

Keywords

EPOXIDATION; PERIODATE; MANGANESE PORPHYRIN; NITROGEN DONORS

Abstract

Effects of imidazoles and substituted pyridines and pure sigma-donors on the oxidation of cyclooctene with NaIO4 by 5,10,15,20-tetraphenylporphyrinatomanganese(III) acetate, Mn(TPP)OAc, and 5,Ia,15,20-tetramesitylporphyrinatomanganese(III) acetate, Mn(TMP)OAc, catalysts in CH2Cl2-H2O solvent are studied Coordination of the nitrogen donors to the Mn-catalysts generally caused a reduction in the epoxidation rates, and an increase in their stabilities toward oxidative degradation. Steric properties of the donors rather than their basicity seems to be more dominating in these oxygenation reaction. The bulky Mn(TMP)OAc showed a greater steric sensitivity than Mn(TPP)OAc.

Cites

INVESTIGATION ON ACTING MECHANISM OF NITROGEN SOURCE IN CULTURE ON MEDIUM PH AND PRODUCTION OF POLY-GAMMA-GLUTAMATE BYFLAVOBACTERIUM SP.

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APA: Copy

MOHAJER, D., & TAYEBEE, R.. (1999). INFLUENCE OF NITROGEN BASES ON EPOXIDATION OF CYCLOOCTENE WITH SODIUM PERIODATE CATALYSED BY MANGANESE(III) PORPHYRINS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 18(1), 27-29. SID. https://sid.ir/paper/532292/en

Vancouver: Copy

MOHAJER D., TAYEBEE R.. INFLUENCE OF NITROGEN BASES ON EPOXIDATION OF CYCLOOCTENE WITH SODIUM PERIODATE CATALYSED BY MANGANESE(III) PORPHYRINS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 1999;18(1):27-29. Available from: https://sid.ir/paper/532292/en

IEEE: Copy

D. MOHAJER, and R. TAYEBEE, “INFLUENCE OF NITROGEN BASES ON EPOXIDATION OF CYCLOOCTENE WITH SODIUM PERIODATE CATALYSED BY MANGANESE(III) PORPHYRINS ,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 18, no. 1, pp. 27–29, 1999, [Online]. Available: https://sid.ir/paper/532292/en

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