ELECTROCHEMICAL PERFORMANCE OF GRAPHITE FELT/EPR MODIFIED CARBON-POLYMER COMPOSITE ELECTRODES (III) EFFECT OF OVERCHARGE ON ELECTRODE DETERIORATION

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HADADIASL V.

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Journal Paper

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Journal: AMIRKABIR Year:2005 | Volume:16 | Issue:62-D Page(s): 45-52

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Title

ELECTROCHEMICAL PERFORMANCE OF GRAPHITE FELT/EPR MODIFIED CARBON-POLYMER COMPOSITE ELECTRODES (III) EFFECT OF OVERCHARGE ON ELECTRODE DETERIORATION

Author(s)

HADADIASL V. | Issue Writer Certificate

Keywords

CONDUCTIVE PLASTICS

VANADIUM BATTERY

COMPOSITE ELECTRODE

Abstract

Conducting plastic electrodes have been developed and investigated for the vanadium redox flow battery. The results have revealed that, due to damage to electrical contact at interface between the felt/composite polymer substrate, the deactivation of graphite felt/composite electrode after severe anodization is irreversible mainly, It was also found that neither electrochemical oxidation of felt nor physical detachments of the felt layer from its substrate is the main reasons for conductive polymer electrodes deterioration. Actually, the polymer destruction under highly oxidizing overcharge V(V) solution is the real mechanism for conductive polymer electrode deterioration. However, the COMPOSITE ELECTRODEs fabricated in this project have proved to be about 10 and 3 times more stable than Toray and graphite fiber filled SEBS COMPOSITE ELECTRODEs respectively under overcharge condition. These electrodes are thus superior to the commercial electrodes for application in the vanadium redox battery.

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APA: Copy

HADADIASL, V.. (2005). ELECTROCHEMICAL PERFORMANCE OF GRAPHITE FELT/EPR MODIFIED CARBON-POLYMER COMPOSITE ELECTRODES (III) EFFECT OF OVERCHARGE ON ELECTRODE DETERIORATION. AMIRKABIR, 16(62-D), 45-52. SID. https://sid.ir/paper/538101/en

Vancouver: Copy

HADADIASL V.. ELECTROCHEMICAL PERFORMANCE OF GRAPHITE FELT/EPR MODIFIED CARBON-POLYMER COMPOSITE ELECTRODES (III) EFFECT OF OVERCHARGE ON ELECTRODE DETERIORATION. AMIRKABIR[Internet]. 2005;16(62-D):45-52. Available from: https://sid.ir/paper/538101/en

IEEE: Copy

V. HADADIASL, “ELECTROCHEMICAL PERFORMANCE OF GRAPHITE FELT/EPR MODIFIED CARBON-POLYMER COMPOSITE ELECTRODES (III) EFFECT OF OVERCHARGE ON ELECTRODE DETERIORATION,” AMIRKABIR, vol. 16, no. 62-D, pp. 45–52, 2005, [Online]. Available: https://sid.ir/paper/538101/en

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