SPECTROPHOTOMETRIC AND ELECTROCHEMICAL STUDY OF THE COMPLEXATION OF IODINE WITH 1,10-DIAZA-18-CROWN-6 IN ACETONITRILE SOLUTION

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SEMNANI A.; SHAREGHI B.; SOVIZI M.R.

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ISSN: 2588-4824

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Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2000 | Volume:19 | Issue:2 Page(s): 67-71

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Title

SPECTROPHOTOMETRIC AND ELECTROCHEMICAL STUDY OF THE COMPLEXATION OF IODINE WITH 1,10-DIAZA-18-CROWN-6 IN ACETONITRILE SOLUTION

Author(s)

SEMNANI A. | SHAREGHI B. | SOVIZI M.R. | Issue Writer Certificate

Keywords

DA18C6 IODINE COMPLEX

SPECTROPHOTOMETRY

FORMATION CONSTANT

CONDUCTOMETRY

BIAMPEROMETRY

Abstract

The complexation reaction between iodine and I,10-Diaza-18-Crown-6 (DA18C6) has been studied in acetonitrile by spectrophotometric, biamperometric and conductometric techniques. The results are indicative of the formation of [(CH3CN)n I+.I-3(-)] from iodine and acetonitrile, and the formation of DA18C6 I+.I- from DA18C6 and [(CH3CN) nI+.I-3] The FORMATION CONSTANT of the latter reaction has been calculated from the absorbance-mole ratio data, using the nonlinear least square program "KINFIT". The IR spectra of acetonitrile-acetonitrile iodine complex and DA18C6-DA18C6 IODINE COMPLEX are compared and the effect of complexation on absorption bands is discussed.

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APA: Copy

SEMNANI, A., SHAREGHI, B., & SOVIZI, M.R.. (2000). SPECTROPHOTOMETRIC AND ELECTROCHEMICAL STUDY OF THE COMPLEXATION OF IODINE WITH 1,10-DIAZA-18-CROWN-6 IN ACETONITRILE SOLUTION . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 19(2), 67-71. SID. https://sid.ir/paper/539894/en

Vancouver: Copy

SEMNANI A., SHAREGHI B., SOVIZI M.R.. SPECTROPHOTOMETRIC AND ELECTROCHEMICAL STUDY OF THE COMPLEXATION OF IODINE WITH 1,10-DIAZA-18-CROWN-6 IN ACETONITRILE SOLUTION . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2000;19(2):67-71. Available from: https://sid.ir/paper/539894/en

IEEE: Copy

A. SEMNANI, B. SHAREGHI, and M.R. SOVIZI, “SPECTROPHOTOMETRIC AND ELECTROCHEMICAL STUDY OF THE COMPLEXATION OF IODINE WITH 1,10-DIAZA-18-CROWN-6 IN ACETONITRILE SOLUTION ,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 19, no. 2, pp. 67–71, 2000, [Online]. Available: https://sid.ir/paper/539894/en

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