مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Information Journal Paper

Title

SYNTHESIS AND PROPERTIES OF NOVEL OPTICALLY ACTIVE AND SOLUBLE AROMATIC/ALIPHATIC POLYIMIDES VIA REACTION OF DIANHYDRIDES AND DIISOCYANATES

Pages

  277-285

Abstract

 Two optically active DIANHYDRIDEs were prepared from the reaction of L-aspartic acid with either pyromellitic DIANHYDRIDE (PMDA) or benzophenone tetracarboxylic DIANHYDRIDE (BTDA) and subsequent transformation of tetraacids to DIANHYDRIDEs using thionyl chloride. Solution POLYCONDENSATION reaction of the prepared DIANHYDRIDEs with different aliphatic and aromatic DIISOCYANATEs (MDI, PPDI, NDI, HMDI, H12MDI and IPDI) resulted in the preparation of twelve novel optically active POLYIMIDEs. The optimal conditions for polyimidations (reaction time and temperature programming) were obtained via study of the model compounds. The resulting POLYIMIDEs showed inherent viscosities in the range of 0.18-0.55 dL/g and showed good solubility in polar aprotic solvents. The monomers, model compounds and polymers were characterized by FTIR, 1HNMR spectroscopies and elemental analysis, and their physical and optical properties were studied as well.

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  • Cite

    APA: Copy

    YEGANEH, H., TAMAMI, B., & GHAZI, IRAJ. (2005). SYNTHESIS AND PROPERTIES OF NOVEL OPTICALLY ACTIVE AND SOLUBLE AROMATIC/ALIPHATIC POLYIMIDES VIA REACTION OF DIANHYDRIDES AND DIISOCYANATES. IRANIAN POLYMER JOURNAL (ENGLISH), 14(3 (57)), 277-285. SID. https://sid.ir/paper/542292/en

    Vancouver: Copy

    YEGANEH H., TAMAMI B., GHAZI IRAJ. SYNTHESIS AND PROPERTIES OF NOVEL OPTICALLY ACTIVE AND SOLUBLE AROMATIC/ALIPHATIC POLYIMIDES VIA REACTION OF DIANHYDRIDES AND DIISOCYANATES. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2005;14(3 (57)):277-285. Available from: https://sid.ir/paper/542292/en

    IEEE: Copy

    H. YEGANEH, B. TAMAMI, and IRAJ GHAZI, “SYNTHESIS AND PROPERTIES OF NOVEL OPTICALLY ACTIVE AND SOLUBLE AROMATIC/ALIPHATIC POLYIMIDES VIA REACTION OF DIANHYDRIDES AND DIISOCYANATES,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 14, no. 3 (57), pp. 277–285, 2005, [Online]. Available: https://sid.ir/paper/542292/en

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