CATALYZED OXIDATION OF CYCLOHEXENE AND CYCLOOCTENE WITH FIRST ROW TRANSITION METALLOPHTHALOCYANINES

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PIROOZMAND M.; SAFARI N.; SAMADI A.A.

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Journal Paper

Paper Information

Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2006 | Volume:25 | Issue:4 Page(s): 85-89

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Information Journal Paper

Title

CATALYZED OXIDATION OF CYCLOHEXENE AND CYCLOOCTENE WITH FIRST ROW TRANSITION METALLOPHTHALOCYANINES

Author(s)

PIROOZMAND M. | SAFARI N. | SAMADI A.A. | Issue Writer Certificate

Keywords

OXIDATION

CYCLOHEXENE

CYCLOOCTENE

PHTHALOCYANINE

CATALYZED OXIDATION

Abstract

First row transition metal complexes of PHTHALOCYANINE are employed as catalysts for the OXIDATION of CYCLOHEXENE and CYCLOOCTENE using iodosylbenzene and pentafluoroiodosyl benzene. The catalysis was performed in dichloromethane:methanol:water (80:18:2) solvent mixture. The products of the catalysis for CYCLOHEXENE are epoxycyclohexane, 2-cyclohexene-1-ol and 2-cyclohexene-1-one whereas for CYCLOOCTENE it is specifically CYCLOOCTENE oxide. For CYCLOHEXENE OXIDATION epoxide yield and selectivity is in the order of MnII > FeIII > FeII > CoII > CrIII > NiII > CuII, while for 2-cyclohexene-1-one production the ability of the catalysts are in the order of NiII > CoII > CuII > CrIII > FeIII > FeII > MnII.

Cites

MONONUCLEAR AND DINUCLEAR COPPER (II) COMPLEXES CONTAINING N, O AND S DONOR LIGANDS: SYNTHESIS, CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION AND ANTIMICROBIAL ACTIVITY OF [CU (PHEN)(TDA)].2H2O AND [(PHEN)2CU (μ-TDA) CU (PHEN)](CLO4)2.1.5H2 O

References

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APA: Copy

PIROOZMAND, M., SAFARI, N., & SAMADI, A.A.. (2006). CATALYZED OXIDATION OF CYCLOHEXENE AND CYCLOOCTENE WITH FIRST ROW TRANSITION METALLOPHTHALOCYANINES. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 25(4), 85-89. SID. https://sid.ir/paper/543676/en

Vancouver: Copy

PIROOZMAND M., SAFARI N., SAMADI A.A.. CATALYZED OXIDATION OF CYCLOHEXENE AND CYCLOOCTENE WITH FIRST ROW TRANSITION METALLOPHTHALOCYANINES. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2006;25(4):85-89. Available from: https://sid.ir/paper/543676/en

IEEE: Copy

M. PIROOZMAND, N. SAFARI, and A.A. SAMADI, “CATALYZED OXIDATION OF CYCLOHEXENE AND CYCLOOCTENE WITH FIRST ROW TRANSITION METALLOPHTHALOCYANINES,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 25, no. 4, pp. 85–89, 2006, [Online]. Available: https://sid.ir/paper/543676/en

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