RECENT ADVANCES IN SYNTHESIS OF NEW POLYMERS BY LIVING FREE RADICAL POLYMERIZATION

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ENTEZAMI A.A.; ABBASIAN MOJTABA

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Iranian Polymer Journal Year:2006 | Volume:15 | Issue:7 (73) Page(s): 583-611

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Information Journal Paper

Title

RECENT ADVANCES IN SYNTHESIS OF NEW POLYMERS BY LIVING FREE RADICAL POLYMERIZATION

Author(s)

ENTEZAMI A.A. | ABBASIAN MOJTABA | Issue Writer Certificate

Keywords

LIVING RADICAL POLYMERIZATION

NITROXIDE MEDIATED POLYMERIZATION

ATOM TRANSFER RADICAL POLYMERIZATION

GRAFT COPOLYMER

BLOCK COPOLYMER

Abstract

This review covers the current status of living free radical polymerization (LFRP) methods and assesses recent advances made especially in the recently years. Three LFRP methods, NITROXIDE MEDIATED POLYMERIZATION (NMP), ATOM TRANSFER RADICAL POLYMERIZATION (ATRP), and reversible-addition fragmentation chain transfer (RAFT), are described and the validity of each method is compared on the basis of the range of polymerizable monomers, reaction conditions, and the ease of chain end group transformation. Living radical graft polymerization of monomers such as styrene onto SBR, ABS, PVC and polystyrene formed by NMP and ATRP will be discussed. Also, the synthesis of block, graft, and hyperbranched copolymers by NMP is covered. Studies using ATRP to synthesize BLOCK COPOLYMERs, bottle brush copolymers, and hydrogels are assessed. Also, the synthesis of star copolymers with alternating hydrophobic and hydrophilic arms is described. For RAFT, the utility of difunctionalized initiators and trithiocarbonates as RAFT agents for ABA BLOCK COPOLYMER formation are described.

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APA: Copy

ENTEZAMI, A.A., & ABBASIAN, MOJTABA. (2006). RECENT ADVANCES IN SYNTHESIS OF NEW POLYMERS BY LIVING FREE RADICAL POLYMERIZATION. IRANIAN POLYMER JOURNAL (ENGLISH), 15(7 (73)), 583-611. SID. https://sid.ir/paper/545826/en

Vancouver: Copy

ENTEZAMI A.A., ABBASIAN MOJTABA. RECENT ADVANCES IN SYNTHESIS OF NEW POLYMERS BY LIVING FREE RADICAL POLYMERIZATION. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2006;15(7 (73)):583-611. Available from: https://sid.ir/paper/545826/en

IEEE: Copy

A.A. ENTEZAMI, and MOJTABA ABBASIAN, “RECENT ADVANCES IN SYNTHESIS OF NEW POLYMERS BY LIVING FREE RADICAL POLYMERIZATION,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 15, no. 7 (73), pp. 583–611, 2006, [Online]. Available: https://sid.ir/paper/545826/en

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