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Information Journal Paper

Title

HIGHLY SELECTIVE PERCHLORATE MEMBRANE ELECTRODE BASED ON SYNTHESIZED SCHIFF BASE COMPLEX

Author(s)

 MAZLOUM ARDAKANI MOHAMMAD | MAZIDI ROUYA | MASHHADIZADEH MOHAMMAD HOSSEIN | NAEIMI HOSSEIN | RABIEI KOBRA | Issue Writer Certificate 

Pages

  123-132

Abstract

 In this work we introduce a practical use of synthesized SCHIFF BASE metal complex in sensing application. A new PERCHLORATE-SELECTIVE ELECTRODE based on the complex N, N' -4-nitrophenylmethanebis- ( salicylaldiminato) copper (II) [CuL] as the membrane carrier was developed. The electrode exhibits a good Nernstian slope of -55.0± 1.0 mV/decade and a linear range of 7.0 ×10 -7 - 1.0 ×10-1M for perchlorate. The limit of detection is 3.0 ×10-7 M. It has a fast response time < 15s and can be used for more than three months. The selective coefficients of PERCHLORATE-SELECTIVE ELECTRODE were determined by the Fixed Interference Method (FIM) and Fixed Primary ion Method (FPM), and could be used in the pH range 4.0-9.0. It was employed as an indicator electrode for direct determination of perchlorate in real samples.

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    • Cite

    APA: Copy

    MAZLOUM ARDAKANI, MOHAMMAD, MAZIDI, ROUYA, MASHHADIZADEH, MOHAMMAD HOSSEIN, NAEIMI, HOSSEIN, & RABIEI, KOBRA. (2010). HIGHLY SELECTIVE PERCHLORATE MEMBRANE ELECTRODE BASED ON SYNTHESIZED SCHIFF BASE COMPLEX. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 29(3), 123-132. SID. https://sid.ir/paper/557909/en

    Vancouver: Copy

    MAZLOUM ARDAKANI MOHAMMAD, MAZIDI ROUYA, MASHHADIZADEH MOHAMMAD HOSSEIN, NAEIMI HOSSEIN, RABIEI KOBRA. HIGHLY SELECTIVE PERCHLORATE MEMBRANE ELECTRODE BASED ON SYNTHESIZED SCHIFF BASE COMPLEX. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2010;29(3):123-132. Available from: https://sid.ir/paper/557909/en

    IEEE: Copy

    MOHAMMAD MAZLOUM ARDAKANI, ROUYA MAZIDI, MOHAMMAD HOSSEIN MASHHADIZADEH, HOSSEIN NAEIMI, and KOBRA RABIEI, “HIGHLY SELECTIVE PERCHLORATE MEMBRANE ELECTRODE BASED ON SYNTHESIZED SCHIFF BASE COMPLEX,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 29, no. 3, pp. 123–132, 2010, [Online]. Available: https://sid.ir/paper/557909/en

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