مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Cites:

2

Information Journal Paper

Title

MANGANESE (III)-BIS(SALICYLALDEHYDE)-4-METHYL-1,2-PHENYLENEDIIMINE (MN-BSMP) AS AN INEXPENSIVE N2O2 TYPE SCHIFF BASE CATALYST FOR OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS WITH (N-BU4NIO4) IN THE PRESENCE OF IMIDAZOL

Pages

  13-18

Abstract

 In this study, bis (salicylaldehyde)-4-methyl-1, 2-phenylenediimine (BSMP) as a SCHIFF BASE ligand of N2O2-type and its Mn and Fe complex as M-BSMP catalyst were synthesized and characterized by UV-Vis, IR spectroscopy and elemental analysis. The efficiency of Fe- and Mn-BSMP catalysts was evaluated in the oxidative DECARBOXYLATION of ARYLACETIC ACIDs with tetra-butylammonium periodate (n-Bu4NIO4) in the presence of imidazol with the mole ratios of M-BSMP: imdazole: n-Bu4NIO4: carboxylic acid of 1: 2: 5: 5, respectively in CH2Cl2. Using Mn-BSMP instead of Fe-BSMP makes the DECARBOXYLATION improved, leading 60-95% of corresponding carbonyl compounds as the sole products.

Cites

References

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  • Cite

    APA: Copy

    KARIMIPOUR, GHOLAMREZA, MONTAZEROZOHORI, MORTEZA, & HAGHIGHAT NAEINI, NASRIN. (2011). MANGANESE (III)-BIS(SALICYLALDEHYDE)-4-METHYL-1,2-PHENYLENEDIIMINE (MN-BSMP) AS AN INEXPENSIVE N2O2 TYPE SCHIFF BASE CATALYST FOR OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS WITH (N-BU4NIO4) IN THE PRESENCE OF IMIDAZOL. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 30(4 (60)), 13-18. SID. https://sid.ir/paper/579765/en

    Vancouver: Copy

    KARIMIPOUR GHOLAMREZA, MONTAZEROZOHORI MORTEZA, HAGHIGHAT NAEINI NASRIN. MANGANESE (III)-BIS(SALICYLALDEHYDE)-4-METHYL-1,2-PHENYLENEDIIMINE (MN-BSMP) AS AN INEXPENSIVE N2O2 TYPE SCHIFF BASE CATALYST FOR OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS WITH (N-BU4NIO4) IN THE PRESENCE OF IMIDAZOL. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2011;30(4 (60)):13-18. Available from: https://sid.ir/paper/579765/en

    IEEE: Copy

    GHOLAMREZA KARIMIPOUR, MORTEZA MONTAZEROZOHORI, and NASRIN HAGHIGHAT NAEINI, “MANGANESE (III)-BIS(SALICYLALDEHYDE)-4-METHYL-1,2-PHENYLENEDIIMINE (MN-BSMP) AS AN INEXPENSIVE N2O2 TYPE SCHIFF BASE CATALYST FOR OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS WITH (N-BU4NIO4) IN THE PRESENCE OF IMIDAZOL,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 30, no. 4 (60), pp. 13–18, 2011, [Online]. Available: https://sid.ir/paper/579765/en

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