POLY VINYL POLY PYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF3); HIGHLY EFFICIENT CATALYST FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS BY H2O2

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MOKHTARI MASOUD; RASTEGAR NIAKI MASOUMEH

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Journal Paper

Paper Information

Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2013 | Volume:32 | Issue:1 (65) Page(s): 43-48

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Title

POLY VINYL POLY PYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF3); HIGHLY EFFICIENT CATALYST FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS BY H2O2

Author(s)

MOKHTARI MASOUD | RASTEGAR NIAKI MASOUMEH | Issue Writer Certificate

Keywords

POLY VINYL POLY PYRROLIDONE

BORON TRIFLUORIDE ETHERATE

HYDROGEN PEROXIDE

ALDEHYDES

CARBOXYLIC ACIDS

ESTERS

Abstract

A highly efficient method for the oxidation of ALDEHYDES to CARBOXYLIC ACIDS using POLY VINYL POLY PYRROLIDONE supported - Boron Trifluoride (PVPP-BF3) in the presence of 35% HYDROGEN PEROXIDE has been developed in acetonitrile at 60oC. This procedure cleanly oxidizes variety of ALDEHYDES to the corresponding CARBOXYLIC ACIDS. Oxidative esterification of benzaldehyde utilizing PVPP-BF3/H2O2 (35%) is also reported in good to excellent yields in acetonitrile at 60oC.

Cites

References

IRON AS A POWERFUL CATALYSTS FOR TRANSITION METAL-CATALYZED REACTIONS

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APA: Copy

MOKHTARI, MASOUD, & RASTEGAR NIAKI, MASOUMEH. (2013). POLY VINYL POLY PYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF₃); HIGHLY EFFICIENT CATALYST FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS BY H₂O₂. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 32(1 (65)), 43-48. SID. https://sid.ir/paper/611232/en

Vancouver: Copy

MOKHTARI MASOUD, RASTEGAR NIAKI MASOUMEH. POLY VINYL POLY PYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF₃); HIGHLY EFFICIENT CATALYST FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS BY H₂O₂. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2013;32(1 (65)):43-48. Available from: https://sid.ir/paper/611232/en

IEEE: Copy

MASOUD MOKHTARI, and MASOUMEH RASTEGAR NIAKI, “POLY VINYL POLY PYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF₃); HIGHLY EFFICIENT CATALYST FOR OXIDATION OF ALDEHYDES TO CARBOXYLIC ACIDS AND ESTERS BY H₂O₂,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 32, no. 1 (65), pp. 43–48, 2013, [Online]. Available: https://sid.ir/paper/611232/en

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