EFFECT OF MIXING CONDITIONS ON MECHANICAL AND PHYSICAL PROPERTIES OF NANOCOMPOSITES BASED ON NBR/PVC/NANOCLAY

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ESMIZADEH E.; NADERI G.; GHOREISHY M.H.R.; BAKHSHANDEH G.R.

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Journal: Iranian Journal of Polymer Science and Technology Year:2010 | Volume:23 | Issue:4 (ISSUE NO. 108) Page(s): 293-304

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Title

EFFECT OF MIXING CONDITIONS ON MECHANICAL AND PHYSICAL PROPERTIES OF NANOCOMPOSITES BASED ON NBR/PVC/NANOCLAY

Author(s)

ESMIZADEH E. | NADERI G. | GHOREISHY M.H.R. | BAKHSHANDEH G.R. | Issue Writer Certificate

Keywords

ACRYLONITRILE BUTADIENE RUBBERQ3

POLY (VINYL CHLORIDE)Q2

NANOCOMPOSITEQ2

MECHANICAL PROPERTIESQ2

RHEOLOGICAL PROPERTIESQ3

Abstract

Mixing conditions of NBR/PVC NANOCOMPOSITEs such as mixing tempera- ture, rotor speed and mixing time are determining parameters in rheologi-cal, mechanical and morphological properties of the compound. Three lev-els were chosen for each parameter using Design Expert software via Box-Behnken method.The NANOCOMPOSITE samples were melt-mixed in Brabender internal mixer. The effect of various mixing parameters such as mixing temperature, rotor speed and mixing time was investigated by stress-strain and rheological curves. The TPE NANOCOMPOSITEs were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic mechanical thermal analysis (DMTA), and MECHANICAL PROPERTIES. It was found that only at low temperature, high tensile strength, storage modulus and low swelling index were obtained by increasing the rotor speed and mixing time simultaneously. As a consequence by increasing the mixing temperature samples undergo two processes. The former is self-crosslinking that leads to torque rise, and the latter is torque drop due to chain sessions. The morphology of nanoclay layers in polymer matrix was studied by X-ray diffraction and TEM. By studying the mechanical and RHEOLOGICAL PROPERTIES of the NANOCOMPOSITEs the optimum preparation condition was found to be the temperature of 160o C, mixing speed of 50 rpm at 6 min.

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APA: Copy

ESMIZADEH, E., NADERI, G., GHOREISHY, M.H.R., & BAKHSHANDEH, G.R.. (2010). EFFECT OF MIXING CONDITIONS ON MECHANICAL AND PHYSICAL PROPERTIES OF NANOCOMPOSITES BASED ON NBR/PVC/NANOCLAY. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), 23(4 (ISSUE NO. 108)), 293-304. SID. https://sid.ir/paper/6183/en

Vancouver: Copy

ESMIZADEH E., NADERI G., GHOREISHY M.H.R., BAKHSHANDEH G.R.. EFFECT OF MIXING CONDITIONS ON MECHANICAL AND PHYSICAL PROPERTIES OF NANOCOMPOSITES BASED ON NBR/PVC/NANOCLAY. IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN)[Internet]. 2010;23(4 (ISSUE NO. 108)):293-304. Available from: https://sid.ir/paper/6183/en

IEEE: Copy

E. ESMIZADEH, G. NADERI, M.H.R. GHOREISHY, and G.R. BAKHSHANDEH, “EFFECT OF MIXING CONDITIONS ON MECHANICAL AND PHYSICAL PROPERTIES OF NANOCOMPOSITES BASED ON NBR/PVC/NANOCLAY,” IRANIAN JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY (PERSIAN), vol. 23, no. 4 (ISSUE NO. 108), pp. 293–304, 2010, [Online]. Available: https://sid.ir/paper/6183/en

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