COPOLYMERIZATION OF SUCCINIC ANHYDRIDE AND EPOXIDE WITH DIETHYLENE GLYCOL SIDE CHAIN

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

FENG LEI; YANG ZHAO; LIU YU.; HAO JIANYUAN; XIONG CHENGDONG; DENG XIANMO

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Iranian Polymer Journal Year:2014 | Volume:23 | Issue:3 Page(s): 217-226

Download Full-Text

View:

256

Download:

Cites:

Information Journal Paper

Title

COPOLYMERIZATION OF SUCCINIC ANHYDRIDE AND EPOXIDE WITH DIETHYLENE GLYCOL SIDE CHAIN

Author(s)

Keywords

ALTERNATING RING-OPENING COPOLYMERIZATION

POLYMERIZATION KINETICS

ALTERNATIVE STRUCTURE

POLYESTER

Abstract

To combine the properties of degradability and low critical solution temperature transition in a single macromolecule, a new thermoresponsive POLYESTER with oligo (ethylene glycol) side chains was designed. This particular polymer P (ME2MO-alt -SA) was prepared by ALTERNATING RING-OPENING COPOLYMERIZATION of functionalized epoxide [2- ((2- (2-methoxyethoxy) ethoxy) methyl) oxirane, ME2MO] and succinic anhydride (SA) in bulk using metallic alkoxide as initiator. The effects of various kinetics conditions on ME2MO–SA copolymerization, such as initiator, polymerization time, temperature, monomer/initiator ratio, and feed ratio, are discussed in detail. The formation of an ALTERNATIVE STRUCTURE is demonstrated and the conditions for ME2MO–SA copolymerization are optimized: aluminum isopropoxide (AIP) as initiator; monomer/initiator molar ratio (M/I) at 150; the feed ratio of comonomers at 0.5; polymerization temperature at 120oC more than 12 h. From the NMR spectra, the initiation end group is confirmed to be isopropanol ester that results from the initiation reaction of AIP with SA. However, the termination end group was variable and could be hydroxyl, carboxyl or their mixture, depending on the feed ratio of ME2MO/SA. Based on the above experimental results, the possible coordination–insertion mechanism was proposed for ALTERNATING RING-OPENING COPOLYMERIZATION of ME2MO and SA initiated by AIP, which suggested the two monomers are inserted into the O-Al and COO-Al active ends alternately.

Multimedia

No record.

Cites

No record.

References

No record.

Cite

APA: Copy

FENG, LEI, YANG, ZHAO, LIU, YU., HAO, JIANYUAN, XIONG, CHENGDONG, & DENG, XIANMO. (2014). COPOLYMERIZATION OF SUCCINIC ANHYDRIDE AND EPOXIDE WITH DIETHYLENE GLYCOL SIDE CHAIN. IRANIAN POLYMER JOURNAL (ENGLISH), 23(3), 217-226. SID. https://sid.ir/paper/634999/en

Vancouver: Copy

FENG LEI, YANG ZHAO, LIU YU., HAO JIANYUAN, XIONG CHENGDONG, DENG XIANMO. COPOLYMERIZATION OF SUCCINIC ANHYDRIDE AND EPOXIDE WITH DIETHYLENE GLYCOL SIDE CHAIN. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2014;23(3):217-226. Available from: https://sid.ir/paper/634999/en

IEEE: Copy

LEI FENG, ZHAO YANG, YU. LIU, JIANYUAN HAO, CHENGDONG XIONG, and XIANMO DENG, “COPOLYMERIZATION OF SUCCINIC ANHYDRIDE AND EPOXIDE WITH DIETHYLENE GLYCOL SIDE CHAIN,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 23, no. 3, pp. 217–226, 2014, [Online]. Available: https://sid.ir/paper/634999/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops