EFFECT OF (3-AMINOPROPYL) TRIMETHOXYSILANE ON MECHANICAL PROPERTIES OF PLA/PBAT BLEND REINFORCED KENAF FIBER

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MOHD SIS ANITH LIYANA; IBRAHIM NOR AZOWA; ZIN WAN YUNUS WAN MD

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Journal Paper

Paper Information

Journal: IRANIAN POLYMER JOURNAL Year:2013 | Volume:22 | Issue:2 Page(s): 101-108

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Title

EFFECT OF (3-AMINOPROPYL) TRIMETHOXYSILANE ON MECHANICAL PROPERTIES OF PLA/PBAT BLEND REINFORCED KENAF FIBER

Author(s)

MOHD SIS ANITH LIYANA | IBRAHIM NOR AZOWA | ZIN WAN YUNUS WAN MD

Keywords

APTMS

BIOCOMPOSITES

MELT BLENDING

COUPLING AGENT

MECHANICAL PROPERTIES

Abstract

The composite-based poly (lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT)/kenaf fiber has been prepared using melt blending method. A PLA/PBAT blend with the ratio of 90:10 wt%, and the same blend ratio reinforced with various amounts of kenaf fiber have been prepared and characterized. However, the addition of kenaf fiber has reduced the mechanical properties sharply due to the poor interaction between the fiber and polymer matrix. Modification of the composite by (3-aminopropyl) trimethoxysilane (APTMS) showed improvements in mechanical properties, increasing up to 42.46, 62.71 and 22.00 % for tensile strength, flexural strength and impact strength, respectively. The composite treated with 2 % APTMS successfully exhibited optimum tensile strength (52.27 MPa), flexural strength (64.27 MPa) and impact strength (234.21 J/m). Morphological interpretation through scanning electron microscopy (SEM) reveals improved interaction and interfacial adhesion between PLA/PBAT blend and kenaf fiber. The fiber was well distributed and remained in the PLA/PBAT blend evenly. DMA results showed lower storage modulus (E′) for PLA/PBAT/kenaf fiber blend and an increase after modification by 2 wt% APTMS. Conversely, the relative damping properties decreased. Based on overall results, APTMS can be used as coupling agent for the composite since APTMS can improve the interaction between hydrophilic natural fibers and non-polar polymers.

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APA: Copy

MOHD SIS, ANITH LIYANA, IBRAHIM, NOR AZOWA, & ZIN WAN YUNUS, WAN MD. (2013). EFFECT OF (3-AMINOPROPYL) TRIMETHOXYSILANE ON MECHANICAL PROPERTIES OF PLA/PBAT BLEND REINFORCED KENAF FIBER. IRANIAN POLYMER JOURNAL (ENGLISH), 22(2), 101-108. SID. https://sid.ir/paper/650815/en

Vancouver: Copy

MOHD SIS ANITH LIYANA, IBRAHIM NOR AZOWA, ZIN WAN YUNUS WAN MD. EFFECT OF (3-AMINOPROPYL) TRIMETHOXYSILANE ON MECHANICAL PROPERTIES OF PLA/PBAT BLEND REINFORCED KENAF FIBER. IRANIAN POLYMER JOURNAL (ENGLISH)[Internet]. 2013;22(2):101-108. Available from: https://sid.ir/paper/650815/en

IEEE: Copy

ANITH LIYANA MOHD SIS, NOR AZOWA IBRAHIM, and WAN MD ZIN WAN YUNUS, “EFFECT OF (3-AMINOPROPYL) TRIMETHOXYSILANE ON MECHANICAL PROPERTIES OF PLA/PBAT BLEND REINFORCED KENAF FIBER,” IRANIAN POLYMER JOURNAL (ENGLISH), vol. 22, no. 2, pp. 101–108, 2013, [Online]. Available: https://sid.ir/paper/650815/en

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