PREPARATION OF CARBON MOLECULAR SIEVES FROM PISTACHIO SHELL AND WALNUT SHELL FOR KINETIC SEPARATION OF CARBON MONOXIDE, HYDROGEN AND METHANE

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MOUSAVI ZAHRA; Bozorgzadeh Hamid Reza

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Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2017 | Volume:36 | Issue:2 Page(s): 71-80

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Title

PREPARATION OF CARBON MOLECULAR SIEVES FROM PISTACHIO SHELL AND WALNUT SHELL FOR KINETIC SEPARATION OF CARBON MONOXIDE, HYDROGEN AND METHANE

Author(s)

MOUSAVI ZAHRA | Bozorgzadeh Hamid Reza | Issue Writer Certificate

Keywords

ADSORPTION

CMS

SEPARATION

KINETIC STUDY

Abstract

In this study, two Carbon Molecular Sieves using Pistachio shell (CMS P) and Walnut shell (CMS W) were prepared by a chemical vapor deposition method and used for pressure swing ADSORPTION and SEPARATION of CO/H2 and CO/CH4. ADSORPTION isotherms of gases obtained for both CMS’s. The Dubinin-Radushkevich isotherm model was used for comparing pore volume of CMS’s. The obtained isotherms for both CMS were compared with Langmuir and Freundlich isotherms. It was observed that Freundlich equation can better correlate the experimental data. ADSORPTION capacity of each CMS and selectivity of them for SEPARATION of CO/H2 and CO/CH4 were obtained with the aid of kinetic studies. In comparison with CMS W, CMS P showed higher ADSORPTION capacity values for gases, but lower selectivity for SEPARATION of them. Finally by fitting experimental data to a pseudo second-order equation, ADSORPTION capacities at equilibrium were obtained for abovementioned gases on both CMS’s.

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APA: Copy

MOUSAVI, ZAHRA, & Bozorgzadeh, Hamid Reza. (2017). PREPARATION OF CARBON MOLECULAR SIEVES FROM PISTACHIO SHELL AND WALNUT SHELL FOR KINETIC SEPARATION OF CARBON MONOXIDE, HYDROGEN AND METHANE. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 36(2), 71-80. SID. https://sid.ir/paper/703943/en

Vancouver: Copy

MOUSAVI ZAHRA, Bozorgzadeh Hamid Reza. PREPARATION OF CARBON MOLECULAR SIEVES FROM PISTACHIO SHELL AND WALNUT SHELL FOR KINETIC SEPARATION OF CARBON MONOXIDE, HYDROGEN AND METHANE. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2017;36(2):71-80. Available from: https://sid.ir/paper/703943/en

IEEE: Copy

ZAHRA MOUSAVI, and Hamid Reza Bozorgzadeh, “PREPARATION OF CARBON MOLECULAR SIEVES FROM PISTACHIO SHELL AND WALNUT SHELL FOR KINETIC SEPARATION OF CARBON MONOXIDE, HYDROGEN AND METHANE,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 36, no. 2, pp. 71–80, 2017, [Online]. Available: https://sid.ir/paper/703943/en

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