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Information Journal Paper

Title

RARE EARTH NITRATE COMPLEXES WITH AN ONO SCHIFF BASE LIGAND: SPECTRAL, THERMAL, LUMINESCENCE AND BIOLOGICAL STUDIES

Pages

  101-109

Abstract

 Five rare earth complexes lanthanum (III), praseodymium (III), neodymium (III), samarium (III) and europium (III) have been synthesized from Schiff base ligand (N, N-bis (2-hydroxy-1-naphthylidene) acetylhydrazone). The complexes were characterized based on elemental analysis, molar conductance, ultraviolet, infrared, mass, thermogravimetric and POWDER X-RAY DIFFRACTION studies. Infrared spectra suggest ligand act as a neutral tridentate ligand. The Schiff base ligand coordinating through the naphtholic oxygen without proton displacement, azomethine nitrogen atom and hydrazone carbonyl oxygen atoms of the ligand to the lanthanide ion.The conductivity and thermal decomposition studies indicate the presence of two coordinated nitrate ion acts as bidentate fashion. POWDER X-RAY DIFFRACTION studies reveal the neodymium complex has an orthorhombic system with different unit cell parameters. Europium, samarium, neodymium and praseodymium complexes exhibit the characteristic luminescence. Further, the in vitro antimicrobial activities of the metal complexes exhibited greater activity as compared with the ligand.

Cites

References

Cite

APA: Copy

VIDYA SAGAR BABU, SRIRAMULA, & HUSSAIN REDDY, KATREDDI. (2017). RARE EARTH NITRATE COMPLEXES WITH AN ONO SCHIFF BASE LIGAND: SPECTRAL, THERMAL, LUMINESCENCE AND BIOLOGICAL STUDIES. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 36(4), 101-109. SID. https://sid.ir/paper/708813/en

Vancouver: Copy

VIDYA SAGAR BABU SRIRAMULA, HUSSAIN REDDY KATREDDI. RARE EARTH NITRATE COMPLEXES WITH AN ONO SCHIFF BASE LIGAND: SPECTRAL, THERMAL, LUMINESCENCE AND BIOLOGICAL STUDIES. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2017;36(4):101-109. Available from: https://sid.ir/paper/708813/en

IEEE: Copy

SRIRAMULA VIDYA SAGAR BABU, and KATREDDI HUSSAIN REDDY, “RARE EARTH NITRATE COMPLEXES WITH AN ONO SCHIFF BASE LIGAND: SPECTRAL, THERMAL, LUMINESCENCE AND BIOLOGICAL STUDIES,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 36, no. 4, pp. 101–109, 2017, [Online]. Available: https://sid.ir/paper/708813/en

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