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Information Journal Paper

Title

The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids

Pages

  97-105

Abstract

 The oxidation of Mandelic acids (MA) to the corresponding oxoacids with Tripropylammonium fluorochromate (TriPAFC) in aqueous acetic acid has been studied. The reaction is first order with respect to [TriPAFC], [MA] and [H+]. The oxidation of α-deuterioMandelic acid shows the presence of a primary kinetic isotope effect (kH/kD = 5. 54 at 303 K). The reaction has been found to be catalyzed by H+ ions. The various thermodynamic parameters for the oxidation have been reported and discussed along with the validity of the isokinetic relationship. The Exner plot showed that all the selected Mandelic acids are oxidized by the same mechanism.

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    • Cite

    APA: Copy

    Shanthi, Shanmugam, Asghar, Basim Hussain, & MANSOOR, SYED SHEIK. (2018). The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 37(3), 97-105. SID. https://sid.ir/paper/712000/en

    Vancouver: Copy

    Shanthi Shanmugam, Asghar Basim Hussain, MANSOOR SYED SHEIK. The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2018;37(3):97-105. Available from: https://sid.ir/paper/712000/en

    IEEE: Copy

    Shanmugam Shanthi, Basim Hussain Asghar, and SYED SHEIK MANSOOR, “The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 37, no. 3, pp. 97–105, 2018, [Online]. Available: https://sid.ir/paper/712000/en

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