Kinetic Study of Ethanol and Methanol Electro-oxidation on Pd-vulcan XC-72R/Cu Electrocatalyst in Alkaline Media

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ZARE MOJTABA; Tabaian Hadi; OMIDVAR HAMID; Saberi Mehr Ali; HOSSEINZADEH GHADER

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Journal Paper

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Journal: JOURNAL OF NANOSTRUCTURES Year:2019 | Volume:9 | Issue:3 Page(s): 539-546

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Title

Kinetic Study of Ethanol and Methanol Electro-oxidation on Pd-vulcan XC-72R/Cu Electrocatalyst in Alkaline Media

Author(s)

Keywords

Direct Alcohol Fuel Cell

Electro-Oxidation

Ethanol

Kinetics

Methanol

Abstract

In this study, palladium nano-particles were electrodeposited galvanostatically on carbon black powder (Vulcan XC-72R). The catalytic activity for Electro-Oxidation of Ethanol and mEthanol in alkaline media were studied by cyclic voltammetry and linear sweep voltammetry techniques. The results indicated that the Electro-Oxidation of Ethanol and mEthanol strongly depends on adsorbed species on the electrocatalyst layer. Effects of Ethanol, mEthanol and KOH concentration on the electrocatalytic properties of the synthesized electrocatalysts during Electro-Oxidation reactions were evaluated by linear sweep voltammetry with various scan rates. The overall rate equations for Ethanol Electro-Oxidation and mEthanol Electro-Oxidation on Palladium /Vulcan in alkaline media were developed. It has been shown that the Pd-C particles with mass loading of 0. 11 mg cm – 2 have superior catalytic activity. Finally, two overall rate equations were developed for EOR and MOR.

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APA: Copy

ZARE, MOJTABA, Tabaian, Hadi, OMIDVAR, HAMID, Saberi Mehr, Ali, & HOSSEINZADEH, GHADER. (2019). Kinetic Study of Ethanol and Methanol Electro-oxidation on Pd-vulcan XC-72R/Cu Electrocatalyst in Alkaline Media. JOURNAL OF NANOSTRUCTURES, 9(3), 539-546. SID. https://sid.ir/paper/745695/en

Vancouver: Copy

ZARE MOJTABA, Tabaian Hadi, OMIDVAR HAMID, Saberi Mehr Ali, HOSSEINZADEH GHADER. Kinetic Study of Ethanol and Methanol Electro-oxidation on Pd-vulcan XC-72R/Cu Electrocatalyst in Alkaline Media. JOURNAL OF NANOSTRUCTURES[Internet]. 2019;9(3):539-546. Available from: https://sid.ir/paper/745695/en

IEEE: Copy

MOJTABA ZARE, Hadi Tabaian, HAMID OMIDVAR, Ali Saberi Mehr, and GHADER HOSSEINZADEH, “Kinetic Study of Ethanol and Methanol Electro-oxidation on Pd-vulcan XC-72R/Cu Electrocatalyst in Alkaline Media,” JOURNAL OF NANOSTRUCTURES, vol. 9, no. 3, pp. 539–546, 2019, [Online]. Available: https://sid.ir/paper/745695/en

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