THEORETICAL STUDIES OF 1, 3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN 7-10 MEMBERED SIMPLE CYCLOALKYNES AND TRIAZOLES R-N3 (R=H, CH3, PH)

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TAHERPOUR AVAT (ARMAN); RAJAEIAN ELAHE; SHAFIEI HADI; MALEKDAR MARYAM

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Seminar Paper

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Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

THEORETICAL STUDIES OF 1, 3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN 7-10 MEMBERED SIMPLE CYCLOALKYNES AND TRIAZOLES R-N3 (R=H, CH3, PH)

Author(s)

TAHERPOUR AVAT (ARMAN) | RAJAEIAN ELAHE | SHAFIEI HADI | MALEKDAR MARYAM

Keywords

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Abstract

THE ENERGY CONTENT IN ALKYNES MAY BE INCREASED FURTHER BY BENDING THE NORMALLY LINEAR TRIPLE BOND, AS IN THE SMALL CYCLOALKYNES. THE STRAIN ENERGY IN THE CYCLOALKYNES INCREASES AS THE SIZE OF THE RING DECREASES. CYCLOADDITIONS OF 1, 3-DIPOLES WITH ALKYNES MAY OCCUR BY CONCERTED MECHANISMS. IN THIS STUDY, THE REACTIVITY AND STRAIN ENERGY EFFECT OF THE CYCLOALKYNES WITH SUBSTITUTED TRIAZOLES R-N3 (R=H, CH3 AND PH) BY THE USE OF B3LYP/6-31G* LEVEL METHOD WILL BE DISCUSSED. THE INVESTIGATION OF THE STRUCTURED PROPERTIES, THEORETICAL THERMODYNAMIC AND KINETIC DATA I.E. DRG, DG* AND RATE CONSTANTS OF THE REACTIONS IN 298K WILL BE PRESENTED.

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APA: Copy

TAHERPOUR, AVAT (ARMAN), RAJAEIAN, ELAHE, SHAFIEI, HADI, & MALEKDAR, MARYAM. (2012). THEORETICAL STUDIES OF 1, 3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN 7-10 MEMBERED SIMPLE CYCLOALKYNES AND TRIAZOLES R-N₃ (R=H, CH₃, PH). IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909474/en

Vancouver: Copy

TAHERPOUR AVAT (ARMAN), RAJAEIAN ELAHE, SHAFIEI HADI, MALEKDAR MARYAM. THEORETICAL STUDIES OF 1, 3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN 7-10 MEMBERED SIMPLE CYCLOALKYNES AND TRIAZOLES R-N₃ (R=H, CH₃, PH). 2012. Available from: https://sid.ir/paper/909474/en

IEEE: Copy

AVAT (ARMAN) TAHERPOUR, ELAHE RAJAEIAN, HADI SHAFIEI, and MARYAM MALEKDAR, “THEORETICAL STUDIES OF 1, 3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN 7-10 MEMBERED SIMPLE CYCLOALKYNES AND TRIAZOLES R-N₃ (R=H, CH₃, PH),” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909474/en

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