FE (III) -CATALYZED CYCLOADDITION REACTION OF IN SITU FORMED IMINES WITH CYCLIC ENOL ETHERS

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BEHBAHANI FARAHNAZ K.; ZIAEI PARISA

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Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

FE (III) -CATALYZED CYCLOADDITION REACTION OF IN SITU FORMED IMINES WITH CYCLIC ENOL ETHERS

Author(s)

BEHBAHANI FARAHNAZ K. | ZIAEI PARISA

Keywords

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Abstract

IRON IS ONE OF THE MOST ABUNDANT AND ENVIRONMENTALLY FRIENDLY METALS ON THE EARTH AND SEVERAL GROUPS HAVE REPORTED VARIOUS IRON METAL-CATALYZED ORGANIC TRANSFORMATIONS DURING THE PAST DECADES.1 IRON CATALYSTS IN ORGANIC REACTIONS HAVE RECENTLY RECEIVED MUCH ATTENTION IN VIEW OF THEIR CHEAPNESS AND ENVIRONMENTAL FRIENDLINESS. AMOUNG THEM FERRIC PERCHLORATE AND FERRIC PERCHLORATE ADSORBED ON SILICA GEL ARE RANKED AS POWERFUL LEWIS ACIDS FOR AFFECTING VARIOUS ORGANIC TRANSFORMATIONS.2LATELY, FERRIC PERCHLORATE ADSORBED ON SILICA GEL HAS ALSO BEEN FOUND TO BE EFFECTIVE FOR THE RAPID ORGANIC FUNCTIONAL GROUP TRANSFORMATIONS SUCH AS DIMERIZATION OF ALKYNES, AROMATIC HYDROCARBONS, SELECTIVE OXIDATION OF THIOLS TO DISULFIDES, AND TRANSANNULAR REACTION IN 1, 5-CYCLOOCTADIENES ON GRINDING USING PESTLE AND MORTAR IN THE SOLID STATE AND ALUMINA-SUPPORTED IRON (III) PERCHLORATE [FE (CLO4) 3.AL2O3] HAVE BEEN EFFECTIVELY USED AS A LEWIS ACID CATALYST FOR NAZAROV CYCLIZATION/MICHAEL ADDITION OF PYRROLE DERIVATIVES.1ON GOING PREVIOUSLY OUR RESEARCH TO INTRODUCE THE CATALYTIC PROTOCOL FOR THE SYNTHESIS OF HETEROCYCLIC COMPOUNDS USING ECO-FRIENDLY CATALYSTS, 3, 4 CATALYTIC SYNTHESIS OF PYRANOAND FURANOQUINOLINES USING ARYL AMINES, 3, 4-DIHYDRO-2H-PYRAN (DHP) AND 2, 3-DIHYDROFURAN (DHF) IS REPORTED IN THE PRESENCE OF LEWIS ACIDS SUCH AS FE (CLO4) 3.6H2O AND FE (CLO4) 3/SIO2) AS CATALYST UNDER MILD CONDITION WITHOUT SOLVENT (SCHEME 1).

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APA: Copy

BEHBAHANI, FARAHNAZ K., & ZIAEI, PARISA. (2012). FE (III) -CATALYZED CYCLOADDITION REACTION OF IN SITU FORMED IMINES WITH CYCLIC ENOL ETHERS. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909477/en

Vancouver: Copy

BEHBAHANI FARAHNAZ K., ZIAEI PARISA. FE (III) -CATALYZED CYCLOADDITION REACTION OF IN SITU FORMED IMINES WITH CYCLIC ENOL ETHERS. 2012. Available from: https://sid.ir/paper/909477/en

IEEE: Copy

FARAHNAZ K. BEHBAHANI, and PARISA ZIAEI, “FE (III) -CATALYZED CYCLOADDITION REACTION OF IN SITU FORMED IMINES WITH CYCLIC ENOL ETHERS,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909477/en

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