THEORETICAL STUDY ON THE HYDROGEN BONDING INTERACTION COMPLEXES OF FORMALDOXIME-HYDROGEN PEROXIDE

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MAKIABADI B.; ZAKARIANEJAD M.; MAHMOODI E.; MEHDIZADEH H.

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Seminar Paper

Paper Information

Seminar: IRANIAN PHYSICAL CHEMISTRY CONFERENCE
Year:2013 | Issue:16

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Title

THEORETICAL STUDY ON THE HYDROGEN BONDING INTERACTION COMPLEXES OF FORMALDOXIME-HYDROGEN PEROXIDE

Author(s)

MAKIABADI B. | ZAKARIANEJAD M. | MAHMOODI E. | MEHDIZADEH H. | Issue Writer Certificate

Keywords

FORMALDOXIME

HYDROGEN BONDING

INTERACTION ENERGY INTRODUCTION

Abstract

FORMALDOXIME, IS THE SIMPLEST MEMBER OF THE OXIMES FAMILY, AN IMPORTANT BIOLOGICAL AND CHEMICAL GROUP OF COMPOUNDS. FORMALDOXIME IN THE CONDENSED PHASE IS READILY TRANSFORMED INTO A SOLID POLYMER (CH2NOH) 3. IN THE ABSENCE OF WATER IT FORMS SALTS WITH ACIDS OF THE TYPE (CH2NOH) 3HCL THAT AFTER HEATING RELEASE MONOMERIC FORMALDOXIME. THE R1R2C=NOH GROUP, CHARACTERISTIC FOR OXIMES, HAS THREE DISTINCT HYDROGEN BONDING SITES AND, SO, OXIMES CAN FORM A VARIETY OF HYDROGEN BONDS. TWO OF THE THREE SITES, THE NITROGEN AND OXYGEN ATOMS, ARE THE HYDROGEN BOND ACCEPTOR SITES AND THE (N) OH GROUP IS A PROTON DONOR. ALTHOUGH THE INTERMOLECULAR HYDROGEN BOND MOTIFS INVOLVING OXIMES PLAY AN IMPORTANT ROLE IN MOLECULAR DESIGN THE HYDROGEN BONDING ABILITIES OF OXIMES WERE MUCH LESS STUDIED. IN THE PRESENT WORK, WE INVESTIGATED THE HYDROGEN BONDING INTERACTION BETWEEN H2O2 AND FORMALDOXIME. HYDROGEN PEROXIDE IS AN UBIQUITOUS MOLECULE AND WELL-KNOWN FOR ITS BACTERICIDAL AND OXIDIZING PROPERTIES. IT PLAYS SIGNIFICANT ROLES IN BIOLOGICAL AND CHEMICAL PROCESSES.

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APA: Copy

MAKIABADI, B., ZAKARIANEJAD, M., MAHMOODI, E., & MEHDIZADEH, H.. (2013). THEORETICAL STUDY ON THE HYDROGEN BONDING INTERACTION COMPLEXES OF FORMALDOXIME-HYDROGEN PEROXIDE. IRANIAN PHYSICAL CHEMISTRY CONFERENCE. SID. https://sid.ir/paper/909522/en

Vancouver: Copy

MAKIABADI B., ZAKARIANEJAD M., MAHMOODI E., MEHDIZADEH H.. THEORETICAL STUDY ON THE HYDROGEN BONDING INTERACTION COMPLEXES OF FORMALDOXIME-HYDROGEN PEROXIDE. 2013. Available from: https://sid.ir/paper/909522/en

IEEE: Copy

B. MAKIABADI, M. ZAKARIANEJAD, E. MAHMOODI, and H. MEHDIZADEH, “THEORETICAL STUDY ON THE HYDROGEN BONDING INTERACTION COMPLEXES OF FORMALDOXIME-HYDROGEN PEROXIDE,” presented at the IRANIAN PHYSICAL CHEMISTRY CONFERENCE. 2013, [Online]. Available: https://sid.ir/paper/909522/en

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