ELECTROCHEMICAL OXIDATION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE FOR THE SYNTHESIS OF A NEW TRIMER

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MALEKI ABBAS; NEMATOLLAHI DAVOOD

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Seminar Paper

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Seminar: IRANIAN BIENNIAL ELECTROCHEMISTRY SEMINAR
Year:2012 | Issue:10

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Title

ELECTROCHEMICAL OXIDATION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE FOR THE SYNTHESIS OF A NEW TRIMER

Author(s)

MALEKI ABBAS | NEMATOLLAHI DAVOOD | Issue Writer Certificate

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Abstract

AN ELECTRON TRANSFER PROCESS TRIGGERS SUBSEQUENT CHEMICAL PROCESSES, SUCH AS BOND DISSOCIATION AND BOND FORMATION. AMONG SEVERAL METHODS FOR ELECTRON-TRANSFER-DRIVEN REACTIONS, THE ELECTROCHEMICAL METHOD SERVES AS A STRAIGHTFORWARD AND POWERFUL METHOD. IN THIS WORK, THE ELECTROCHEMICAL TRIMERIZATION OFN, N -DIMETHYL- P -PHENYLENEDIAMINE VIA ANODIC OXIDATION OF N, N DIMETHYL- P-PHENYLENEDIAMINE IS DESCRIBED. THE MECHANISM OF TRIMERIZATION HAS BEEN STUDIED IN AQUEOUS SOLUTION USING CYCLIC VOLTAMMETRY AND CONTROLLED-POTENTIAL COULOMETRY. THE RESULTS OF THIS WORK SHOW THAT N, N -DIMETHYL- P -PHENYLENEDIAMINE IS OXIDIZED IN AQUEOUS SOLUTIONS TO CORRESPONDING QUININE-DIIMINE. THE QUINONE-DIIMINE PARTICIPATES IN TRIMERIZATION REACTION. IT SEEMS THAT THE MICHAEL REACTION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE TO CORRESPONDING QUININEDIIMINE LEADS TO THE FORMATION OF TRIMER AS FINAL PRODUCT. THE ELECTROCHEMICAL SYNTHESIS OF “N, N DIMETHYL- P-PHENYLENEDIAMINE-TRIMER” HAS BEEN SUCCESSFULLY PERFORMED IN AN UNDIVIDED CELL IN A GOOD YIELD AND PURITY. THE PRESENTED WORK REPRESENTS A FACILE, REAGENT-LESS, AND ENVIRONMENTALLY FRIENDLY METHOD WITH HIGH ATOM ECONOMY, FOR THE SYNTHESIS OF A UNIQUE TRIMER OF N, N -DIMETHYL- P PHENYLENEDIAMINE USING A CARBON ELECTRODE.

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APA: Copy

MALEKI, ABBAS, & NEMATOLLAHI, DAVOOD. (2012). ELECTROCHEMICAL OXIDATION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE FOR THE SYNTHESIS OF A NEW TRIMER. IRANIAN BIENNIAL ELECTROCHEMISTRY SEMINAR. SID. https://sid.ir/paper/909734/en

Vancouver: Copy

MALEKI ABBAS, NEMATOLLAHI DAVOOD. ELECTROCHEMICAL OXIDATION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE FOR THE SYNTHESIS OF A NEW TRIMER. 2012. Available from: https://sid.ir/paper/909734/en

IEEE: Copy

ABBAS MALEKI, and DAVOOD NEMATOLLAHI, “ELECTROCHEMICAL OXIDATION OF N, N -DIMETHYL- P -PHENYLENEDIAMINE FOR THE SYNTHESIS OF A NEW TRIMER,” presented at the IRANIAN BIENNIAL ELECTROCHEMISTRY SEMINAR. 2012, [Online]. Available: https://sid.ir/paper/909734/en

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