Oxygenated additives are added to the base gasoline for such purposes like increase in Octane Number, improvement of engine performance and decease in exhaust emissions. In Iran, Methyl Tertiary Butyl Ether (MTBE) is used as an additive to the base gasoline. Due to the destructive environmental effects of the mentioned material, our country, the same as other developed countries, should seek to use a replacement for the mentioned additive. The combination of the base gasoline and fuel additives has such limitations like increase in the quantity of (Volatility), the reid vapor pressure (RVP) and decrease in calorific value of the fuel obtained. In this research, Ethanol, Tertiary Butyl Alcohol (TBA) and Metyl Tertiary Butyl Ether, in the volumetric ratios of 2.5, 5, 7.5, 10, 15 and 20, are blended with the base gasoline of Tehran Oil Refinery Company (TORC). The behavior of (Volatility) of the obtained fuel has been investigated based on ASTM standards. The results obtained from the done investigation reveal that in case of using Ethanol as a fuel additive, certain changes should be made in the formulation of base gasoline. The mentioned combination has an undesirable effect on the other characteristics of fuel such as Octane Number. Addition of Tertiary Butyl Alcohol to gasoline shall result in trivial increase in the reid vapor pressure. Consequently, there will be no need for the replacement of light straight run gasoline (LSRG) compounds with heavier compounds in order to decrease the reid vapor pressure.